| Autor: |
Hou X; Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China.; Institute of Zhejiang University-Quzhou, Zhejiang Provincial Innovation Center of Advanced Chemicals Technology, Quzhou, Zhejiang 324000, China., Shen F; Zhejiang Youngdream Li-ion Co., Ltd., Quzhou, Zhejiang 324000, China., Chen M; Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China.; Institute of Zhejiang University-Quzhou, Zhejiang Provincial Innovation Center of Advanced Chemicals Technology, Quzhou, Zhejiang 324000, China., Song L; Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China., Liu Q; Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China.; Institute of Zhejiang University-Quzhou, Zhejiang Provincial Innovation Center of Advanced Chemicals Technology, Quzhou, Zhejiang 324000, China., Ren Y; Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China.; Institute of Zhejiang University-Quzhou, Zhejiang Provincial Innovation Center of Advanced Chemicals Technology, Quzhou, Zhejiang 324000, China., Zhan X; Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China.; Institute of Zhejiang University-Quzhou, Zhejiang Provincial Innovation Center of Advanced Chemicals Technology, Quzhou, Zhejiang 324000, China., Zhang Q; Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, Zhejiang 310027, China.; Institute of Zhejiang University-Quzhou, Zhejiang Provincial Innovation Center of Advanced Chemicals Technology, Quzhou, Zhejiang 324000, China. |
| Abstrakt: |
Thermal conduction for electronic devices has attracted extensive attention in light of the development of 5G communication. Thermally conductive materials with high thermal conductivity and extensive mechanical flexibility are extremely desirable in practical applications. However, the construction of efficient interconnected conductive pathways and continuous conductive networks is inadequate for either processing or actual usage in existing technologies. In this work, spherical copper nanoparticles (S-CuNPs) and urchin-inspired fractal-growth CuNPs (U-CuNPs), thermally conductive metal fillers induced by ionic liquids, were fabricated successfully through the electrochemical deposition method. Compared to S-CuNPs, the U-CuNPs shows larger specific surface contact area, thus making it easier to build a continuous conductive pathway network in the corresponding U-CuNPs/liquid silicone rubber (LSR) thermally conductive composites. The optimal loading of CuNP fillers was determined by evaluating the rheological performance of the prepolymer and the mechanical properties and thermal conductivity performances of the composites. When the filler loading is 150 phr, the U-CuNPs/LSR produces optimal mechanical properties (e.g., tensile strength and modulus), thermal conductivity (above 1000% improvement compared to pure LSR), and heating/cooling efficiency. The enhanced thermal conductivity of U-CuNPs/LSR was also confirmed through the finite element analysis (FEA) overall temperature distribution, indicating that U-CuNPs with larger specific surface contact areas exhibit more advantages in forming a continuous network in composites than S-CuNPs, making U-CuNPs/LSR a promising and competitive alternative to traditional flexible thermally interface materials. |
