| Autor: |
Li WL; Department of NanoEngineering, University of California San Diego La Jolla, CA 92093, USA. wal019@ucsd.edu.; Program of Materials Science and Engineering, University of California San Diego, La Jolla, CA 92093, USA., Burkhardt J; Department of NanoEngineering, University of California San Diego La Jolla, CA 92093, USA. wal019@ucsd.edu.; Department of Chemistry and Biochemistry, University of California San Diego La Jolla, CA 92093, USA. |
| Jazyk: |
angličtina |
| Zdroj: |
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2024 Jun 06; Vol. 26 (22), pp. 16091-16095. Date of Electronic Publication: 2024 Jun 06. |
| DOI: |
10.1039/d4cp01646g |
| Abstrakt: |
In light of recently reported monovalent lanthanide in borozene complexes LnB 8 - (Ln = La, Pr, Tb, Tm, Yb), the corresponding AnB 8 - (An = Ac, Pa, Bk, Md, No) actinide species within the same group were theoretically investigated in respect of oxidation state, stability, electronic structure and chemical bonding pattern. Our investigations reveal the feasibility of actinides, especially for the late actinide borozene compounds (BkB 8 - , MdB 8 - , NoB 8 - ) adopting a monovalent oxidation state of +I, a phenomenon fine-tuned by the doubly aromatic borozene B 8 2- . Early actinides (AcB 8 - , PaB 8 - ) however exhibit a tendency towards higher trivalent oxidation states. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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