| Autor: |
Crawford CA; Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, U.K., Hiley CI; Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, U.K., Scott CAM; Centre for Materials Physics, Durham University, South Road, Durham DH1 3LE, U.K., Ritter C; Institut Laue-Langevin, 71 avenue des Matyrs, CS 20156, 38042 Grenoble cedex 9, France., Lees MR; Department of Physics, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, U.K., Bristowe NC; Centre for Materials Physics, Durham University, South Road, Durham DH1 3LE, U.K., Walton RI; Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, U.K., Senn MS; Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry CV4 7AL, U.K. |
| Abstrakt: |
We report a new nickel hydroxyfluoride diaspore Ni(OH)F prepared using hydrothermal synthesis from NiCl 2 ·6H 2 O and NaF. Magnetic characterization reveals that, contrary to other reported transition-metal hydroxyfluoride diaspores, Ni(OH)F displays weak ferromagnetism below the magnetic ordering temperature. To understand this difference, neutron diffraction is used to determine the long-range magnetic structure. The magnetic structure is found to be distinct from those reported for other hydroxyfluoride diaspores and shows an antiferromagnetic spin ordering in which ferromagnetic canting is allowed by symmetry. Furthermore, neutron powder diffraction on a deuterated sample, Ni(OD)F, reveals partial anion ordering that is distinctive to what has previously been reported for Co(OH)F and Fe(OH)F. Density functional theory calculations show that OH/F ordering can have a directing influence on the lowest energy magnetic ground state. Our results point toward a subtle interplay between the sign of magnetic exchange interactions, the electronic configuration, and anion disordering. |
