Electrochemical Formation of Ionic Porous Organic Polymers Based on Viologen for Electrochromic Applications.

Autor: Shao M; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China., Dong J; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China., Lv X; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China., Liu C; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China., Xia M; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China., Cui J; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China., Tameev A; The Laboratory for Electronic and Photonic Processes in Polymer Nanocomposites, Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Moscow, 119071, Russia., Ouyang M; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China., Zhang C; International Science & Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China.
Jazyk: angličtina
Zdroj: Macromolecular rapid communications [Macromol Rapid Commun] 2024 Jul; Vol. 45 (13), pp. e2400031. Date of Electronic Publication: 2024 Apr 19.
DOI: 10.1002/marc.202400031
Abstrakt: The systematic study of two ionic porous organic polymers (iPOPs) based on viologens and their first applications in the electrochromic field are reported. The viologen-based iPOPs are synthesized by electrochemical polymerization with cyano groups, providing a simple and controllable method for iPOPs that solves the film preparation problems common to viologens. After the characterization of these iPOPs, a detailed study of their electrochromic properties is conducted. The iPOP films based on viologens structure exhibit excellent electrochromic properties. In addition, the resulting iPOP films show high sensitivity to electrolyte ions of different sizes in the redox process. Electrochemical and electrochromic data of the iPOPs explain this phenomenon in detail. These results demonstrate that iPOPs of this type are ideal candidates as electrochromic materials due to their inherent porous structures and ion-rich properties.
(© 2024 Wiley‐VCH GmbH.)
Databáze: MEDLINE
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