| Autor: |
Fan B; Shenzhen Key Laboratory of Advanced Thin Films and Applications, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China., Fang Y; Shenzhen Key Laboratory of Advanced Thin Films and Applications, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China., Xue B; Shenzhen Key Laboratory of Advanced Thin Films and Applications, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China., Wu Q; College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China., Luo Z; College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China., Zhang X; University of Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) UMR 6226, Rennes 35042, France., Calvez L; University of Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) UMR 6226, Rennes 35042, France., Wu L; College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China.; University of Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) UMR 6226, Rennes 35042, France. |
| Abstrakt: |
Flexible solid-state batteries fabricated by printing techniques are promising integrated power supplies for miniaturized and customized electronic devices. While typically these batteries use polymer solid electrolytes, a flexible Li 2 S cathode with sulfide solid electrolyte is spray-printed in this work, by using solvated Li 3 PS 4 nanoparticles as inorganic ion-conductive binder. This benefits from a novel low-temperature-sintering property of these nanoparticles, which can be pressure-free densified, along with the desolvation process, and thus bind the cathode at 250 °C. The battery can be stably charged and discharged for 300 cycles with no stacking pressure, and the capacity maintains at 840 mA h g Li2 S -1 . We believe this low-temperature-sintering phenomenon of solid electrolyte nanoparticles will open a new path toward the application of sulfide solid electrolytes in printed solid-state batteries. |
