| Autor: |
Giuso V; Université de Strasbourg, CNRS Institut de Physique et Chimie des Matériaux de Strasbourg, UMR 7504 23 rue du Loess, 67034 Strasbourg, France. mauro@unistra.fr., Gourlaouen C; Laboratoire de Chimie Quantique Université de Strasbourg CNRS UMR7177 Institut Le Bel 4 Rue Blaise Pascal, 67000 Strasbourg, France. c.daniel@unistra.fr., Delporte-Pébay M; Université de Rennes, CNRS, ISCR - UMR 6226, 35000 Rennes, France. jeanne.crassous@univ-rennes1.fr., Groizard T; Laboratoire de Chimie Quantique Université de Strasbourg CNRS UMR7177 Institut Le Bel 4 Rue Blaise Pascal, 67000 Strasbourg, France. c.daniel@unistra.fr., Vanthuyne N; Aix Marseille University, CNRS Centrale Marseille, iSm2, 13284 Marseille, France., Crassous J; Université de Rennes, CNRS, ISCR - UMR 6226, 35000 Rennes, France. jeanne.crassous@univ-rennes1.fr., Daniel C; Laboratoire de Chimie Quantique Université de Strasbourg CNRS UMR7177 Institut Le Bel 4 Rue Blaise Pascal, 67000 Strasbourg, France. c.daniel@unistra.fr., Mauro M; Université de Strasbourg, CNRS Institut de Physique et Chimie des Matériaux de Strasbourg, UMR 7504 23 rue du Loess, 67034 Strasbourg, France. mauro@unistra.fr. |
| Abstrakt: |
The design of enantiomerically pure circularly polarized luminescent (CPL) emitters would enormously benefit from the accurate and in-depth interpretation of the chiroptical properties by means of jointly (chiroptical) photophysical measurements and state-of-the-art theoretical investigation. Herein, computed and experimental (chiro-)optical properties of a series of eight enantiopure phosphorescent rhenium(I) tricarbonyl complexes are systematically compared in terms of electronic circular dichroism (ECD) and CPL. The compounds have general formula fac -[ReX(CO) 3 (N^C NHC )], where N^C NHC is a pyridyl benzannulated N-heterocyclic carbene deriving from a (substituted) 2-(pyridin-2-yl)imidazo[1,5- a ]pyridin-2-ium proligand and X = Cl, Br and I, and display structured red phosphorescence with long-lived ( τ = 7.0-19.1 μs) excited-state lifetime and dissymmetry factors | g Lum | up to 4 × 10 -3 . The mixing of the character of the lowest-lying emitting triplet excited state is finely modulated between ligand centred ( 3 LC), metal-to-ligand charge transfer ( 3 MLCT) and halogen-to-ligand charge transfer ( 3 XLCT) by the nature of the ancillary halogen and the chromophoric N^C NHC ligand. The study unravels the effect exerted by the nature of the excited state onto the ECD and CPL activity and will help to pave the way to construct efficient CPL emitters by chemical design. |
