N , N -Bis(9-methyl-3-carbazolyl)-4-anisidine as an Electroactive Material for Use in Perovskite Solar Cells.

Autor:	Keruckas J; Department of Polymer Chemistry and Technology, Kaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania., Janasik P; Department of Physical Chemistry and Technology of Polymers, Silesian University of Technology, Strzody 9, Gliwice 44-100, Poland.; Centre for Organic and Nanohybrid Electronics, Silesian University of Technology, Konarskiego 22b, 44-100 Gliwice, Poland., Keruckienė R; Department of Polymer Chemistry and Technology, Kaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.; Department of Physical Chemistry and Technology of Polymers, Silesian University of Technology, Strzody 9, Gliwice 44-100, Poland., Czulkin P; Department of Physical Chemistry and Technology of Polymers, Silesian University of Technology, Strzody 9, Gliwice 44-100, Poland.; Centre for Organic and Nanohybrid Electronics, Silesian University of Technology, Konarskiego 22b, 44-100 Gliwice, Poland., Czichy M; Department of Physical Chemistry and Technology of Polymers, Silesian University of Technology, Strzody 9, Gliwice 44-100, Poland.; Centre for Organic and Nanohybrid Electronics, Silesian University of Technology, Konarskiego 22b, 44-100 Gliwice, Poland., Lapkowski M; Department of Physical Chemistry and Technology of Polymers, Silesian University of Technology, Strzody 9, Gliwice 44-100, Poland.; Centre for Organic and Nanohybrid Electronics, Silesian University of Technology, Konarskiego 22b, 44-100 Gliwice, Poland.; Centre of Polymer and Carbon Materials, Polish Academy of Sciences Zabrze, M. Curie-Sklodowskiej 34, 41-819 Zabrze, Poland., Volyniuk D; Department of Polymer Chemistry and Technology, Kaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania., Durgaryan R; Department of Polymer Chemistry and Technology, Kaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.; Department of Chemistry - Ångström Laboratory, Physical Chemistry, Uppsala University, Ångströmlaboratoriet, Lägerhyddsvägen 1, 751 20 Uppsala, Sweden., Kim BJ; Department of Chemistry - Ångström Laboratory, Physical Chemistry, Uppsala University, Ångströmlaboratoriet, Lägerhyddsvägen 1, 751 20 Uppsala, Sweden., Boschloo G; Department of Chemistry - Ångström Laboratory, Physical Chemistry, Uppsala University, Ångströmlaboratoriet, Lägerhyddsvägen 1, 751 20 Uppsala, Sweden., Gražulevičius JV; Department of Polymer Chemistry and Technology, Kaunas University of Technology, Baršausko 59, Kaunas 51423, Lithuania.
Jazyk:	angličtina
Zdroj:	ACS applied energy materials [ACS Appl Energy Mater] 2023 May 16; Vol. 6 (11), pp. 5720-5728. Date of Electronic Publication: 2023 May 16 (Print Publication: 2023).
DOI:	10.1021/acsaem.3c00102
Abstrakt:	Di(9-methyl-3-carbazolyl)-(4-anisyl)amine is presented as an effective hole-transporting material suitable for application in perovskite solar cells. It is obtained by a three-step synthesis from inexpensive starting compounds. It has a relatively high glass transition temperature of 93 °C and thermal stability with 5% weight loss at 374 °C. The compound exhibits reversible double-wave electrochemical oxidation below +1.5 V and polymerization at higher potential. A mechanism for its oxidation is proposed based on electrochemical impedance and electron spin resonance spectroscopy investigations, ultraviolet-visible-near-infrared absorption spectroelectrochemistry results, and density functional theory-based calculations. Vacuum-deposited films of the compound are characterized by a low ionization potential of 5.02 ± 0.06 eV and hole mobility of 10 -3 cm 2 /(Vs) at an electric field of 4 × 10 5 V/cm. The newly synthesized compound has been used to fabricate dopant-free hole-transporting layers in perovskite solar cells. A power conversion efficiency of 15.5% was achieved in a preliminary study. Competing Interests: The authors declare no competing financial interest. (© 2023 The Authors. Published by American Chemical Society.)
Databáze:	MEDLINE
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