Iodine-mediated photoinduced tuneable disulfonylation and sulfinylsulfonylation of alkynes with sodium arylsulfinates.

Autor:	Reddy MB; Centre for Synthesis & Chemical Biology, UCD School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland. eoghan.mcgarrigle@ucd.ie.; A2P CDT in Sustainable Chemistry and BiOrbic Bioeconomy SFI Research Centre, University College Dublin, Belfield, Dublin 4, Ireland., McGarrigle EM; Centre for Synthesis & Chemical Biology, UCD School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland. eoghan.mcgarrigle@ucd.ie.; A2P CDT in Sustainable Chemistry and BiOrbic Bioeconomy SFI Research Centre, University College Dublin, Belfield, Dublin 4, Ireland.
Jazyk:	angličtina
Zdroj:	Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Jun 20; Vol. 59 (50), pp. 7767-7770. Date of Electronic Publication: 2023 Jun 20.
DOI:	10.1039/d3cc02011h
Abstrakt:	An efficient transition-metal free iodine-mediated tuneable disulfonylation and sulfinylsulfonylation of alkynes with sodium arylsulfinates under visible light irradiation has been developed. This photochemical protocol offers broad substrate scope of 1,2-bissulfonylethenes with high functional group tolerance and good yields under mild reaction conditions. In addition, it was found that β-sulfinyl alkenylsulfones can be obtained in the absence of base. It is proposed that the reactions proceed via sulfonyl and sulfinyl radicals.
Databáze:	MEDLINE
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