Metal-free visible-light-promoted C(sp 3 )-H functionalization of aliphatic cyclic ethers using trace O 2 .
| Autor: | Niu B; Department of Chemistry and Chemical Biology, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA., Blackburn BG; Department of Chemistry and Chemical Biology, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA., Sachidanandan K; Department of Chemistry and Chemical Biology, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA., Cooke MV; Department of Chemistry and Chemical Biology, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA., Laulhé S; Department of Chemistry and Chemical Biology, Indiana University-Purdue University Indianapolis, Indianapolis, IN 46202, USA. |
|---|---|
| Jazyk: | angličtina |
| Zdroj: | Green chemistry : an international journal and green chemistry resource : GC [Green Chem] 2021 Dec 07; Vol. 23 (23), pp. 9454-9459. Date of Electronic Publication: 2021 Nov 05. |
| DOI: | 10.1039/d1gc03482k |
| Abstrakt: | Presented is a light-promoted C-C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This transformation proceeds in neat conditions through an auto-oxidation mechanism which is maintained through the leaching of trace amounts of O Competing Interests: Conflicts of interest There are no conflicts to declare. |
| Databáze: | MEDLINE |
| Externí odkaz: |
|