| Autor: |
Herrera SE; Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, CONICET. Facultad de Ciencias Exactas y Naturales. Ciudad Universitaria, Pabellón 2, Buenos Aires C1428EHA, Argentina. sherrera@qi.fcen.uba.ar., Agazzi ML; Instituto para el Desarrollo Agroindustrial y de la Salud (IDAS), (UNRC, CONICET), Ruta Nacional 36 KM 601, 5800 Río Cuarto, Argentina. magazzi@exa.unrc.edu.ar., Apuzzo E; Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), (UNLP, CONICET), Sucursal 4, Casilla de Correo 16, 1900 La Plata, Argentina. omarazzaroni@quimica.unlp.edu.ar., Cortez ML; Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), (UNLP, CONICET), Sucursal 4, Casilla de Correo 16, 1900 La Plata, Argentina. omarazzaroni@quimica.unlp.edu.ar., Marmisollé WA; Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), (UNLP, CONICET), Sucursal 4, Casilla de Correo 16, 1900 La Plata, Argentina. omarazzaroni@quimica.unlp.edu.ar., Tagliazucchi M; Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, CONICET. Facultad de Ciencias Exactas y Naturales. Ciudad Universitaria, Pabellón 2, Buenos Aires C1428EHA, Argentina. sherrera@qi.fcen.uba.ar., Azzaroni O; Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), (UNLP, CONICET), Sucursal 4, Casilla de Correo 16, 1900 La Plata, Argentina. omarazzaroni@quimica.unlp.edu.ar. |
| Abstrakt: |
The complexation of polyelectrolytes with other oppositely charged structures gives rise to a great variety of functional materials with potential applications in a wide spectrum of technological fields. Depending on the assembly conditions, polyelectrolyte complexes can acquire different macroscopic configurations such as dense precipitates, nanosized colloids and liquid coacervates. In the past 50 years, much progress has been achieved to understand the principles behind the phase separation induced by the interaction of two oppositely charged polyelectrolytes in aqueous solutions, especially for symmetric systems (systems in which both polyions have similar molecular weight and concentration). However, in recent years, the complexation of polyelectrolytes with alternative building blocks such as small charged molecules (multivalent inorganic species, oligopeptides, and oligoamines, among others) has gained attention in different areas. In this review, we discuss the physicochemical characteristics of the complexes formed by polyelectrolytes and multivalent small molecules, putting a special emphasis on their similarities with the well-known polycation-polyanion complexes. In addition, we analyze the potential of these complexes to act as versatile functional platforms in various technological fields, such as biomedicine and advanced materials engineering. |
