Fe 3 O 4 supported UiO-66 (Zr) metal-organic framework for removal of drug contaminants from water: fuzzy logic modeling approach.

Autor: Civan Çavuşoğlu F; Department of Chemical Engineering, Faculty of Engineering & Architecture, Beykent University, Sarıyer, Istanbul, 34396, Turkey., Özçelik G; Department of Chemical Engineering, Faculty of Engineering & Architecture, Beykent University, Sarıyer, Istanbul, 34396, Turkey., Özbek C; Department of Mechanical Engineering, Faculty of Engineering & Architecture, Beykent University, Sarıyer, Istanbul, 34396, Turkey., Özkara-Aydınoğlu Ş; Department of Chemical Engineering, Faculty of Engineering & Architecture, Beykent University, Sarıyer, Istanbul, 34396, Turkey., Bayazit ŞS; Department of Chemical Engineering, Faculty of Engineering & Architecture, Beykent University, Sarıyer, Istanbul, 34396, Turkey. sahikasena@gmail.com.
Jazyk: angličtina
Zdroj: Environmental science and pollution research international [Environ Sci Pollut Res Int] 2023 Mar; Vol. 30 (15), pp. 44337-44352. Date of Electronic Publication: 2023 Jan 24.
DOI: 10.1007/s11356-023-25378-x
Abstrakt: The increase in production and consumption of pharmaceuticals and personal care products causes environmental problems. In this study, naproxen and clofibric acid adsorption were studied using Fe 3 O 4 -supported UiO-66 (Zr) metal-organic framework (Mag-UiO-66). The adsorption processes were carried out in batch mode at pH value 3.0. The optimum adsorbent quantities, equilibrium periods, pseudo-first-order (PFO), pseudo-second-order (PSO), and intra-particles diffusion kinetic models were calculated. Non-linear Langmuir, Freundlich, Dubinin-Radushkevich (D-R), and Sips isotherm equations were applied to experimental data. Thermodynamic analyses of naproxen and clofibric acid adsorption were also carried out in this study. The Langmuir isotherm q m values were found as 14.15 mg/g for naproxen at 308 K and 41.87 mg/g for clofibric acid at 298 K. Both of the adsorption processes were exothermic. MISO (multi-input single-output) fuzzy logic models for removal of both naproxen and clofibric acid adsorptions were designed based on the experimental data to estimate the removal uptake values. It is noteworthy that the results obtained through designed fuzzy logic models matched well with the experimental data and the findings of this study emphasize the validity of designed fuzzy logic models.
(© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)
Databáze: MEDLINE
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