Nanosegregation in arene-perfluoroarene π-systems for hybrid layered Dion-Jacobson perovskites.

Autor: Almalki M; Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. michael.graetzel@epfl.ch., Dučinskas A; Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. michael.graetzel@epfl.ch.; Max Planck Institute for Solid State Research, 70569 Stuttgart, Germany., Carbone LC; Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. michael.graetzel@epfl.ch., Pfeifer L; Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. michael.graetzel@epfl.ch., Piveteau L; Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland., Luo W; Adolphe Merkle Institute, University of Fribourg, 1700 Fribourg, Switzerland. jovana.milic@unifr.ch., Lim E; Adolphe Merkle Institute, University of Fribourg, 1700 Fribourg, Switzerland. jovana.milic@unifr.ch., Gaina PA; Adolphe Merkle Institute, University of Fribourg, 1700 Fribourg, Switzerland. jovana.milic@unifr.ch., Schouwink PA; Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1951 Sion, Switzerland., Zakeeruddin SM; Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. michael.graetzel@epfl.ch., Milić JV; Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. michael.graetzel@epfl.ch.; Adolphe Merkle Institute, University of Fribourg, 1700 Fribourg, Switzerland. jovana.milic@unifr.ch., Grätzel M; Laboratory of Photonics and Interfaces, Institute of Chemistry and Chemical Engineering, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland. michael.graetzel@epfl.ch.
Jazyk: angličtina
Zdroj: Nanoscale [Nanoscale] 2022 May 16; Vol. 14 (18), pp. 6771-6776. Date of Electronic Publication: 2022 May 16.
DOI: 10.1039/d1nr08311b
Abstrakt: Layered hybrid perovskites are based on organic spacers separating hybrid perovskite slabs. We employ arene and perfluoroarene moieties based on 1,4-phenylenedimethylammonium (PDMA) and its perfluorinated analogue (F-PDMA) in the assembly of hybrid layered Dion-Jacobson perovskite phases. The resulting materials are investigated by X-ray diffraction, UV-vis absorption, photoluminescence, and solid-state NMR spectroscopy to demonstrate the formation of layered perovskite phases. Moreover, their behaviour was probed in humid environments to reveal nanoscale segregation of layered perovskite species based on PDMA and F-PDMA components, along with enhanced stabilities of perfluoroarene systems, which is relevant to their application.
Databáze: MEDLINE
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