The Dynamic Covalent Chemistry of Amidoboronates: Tuning the rac 5 /rac 6 Ratio via the B-N and B-O Dynamic Covalent Bonds.

Autor: Harders P; Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, 24098, Kiel, Germany., Griebenow T; Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, 24098, Kiel, Germany., Businski A; Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, 24098, Kiel, Germany., Kaus AJ; Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, 24098, Kiel, Germany., Pietsch L; Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, 24098, Kiel, Germany., Näther C; Institute of Inorganic Chemistry, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Straße 2, 24118, Kiel, Germany., McConnell AJ; Otto Diels Institute of Organic Chemistry, Christian-Albrechts-Universität zu Kiel, Otto-Hahn-Platz 4, 24098, Kiel, Germany.
Jazyk: angličtina
Zdroj: ChemPlusChem [Chempluschem] 2022 May; Vol. 87 (5), pp. e202200085. Date of Electronic Publication: 2022 Mar 22.
DOI: 10.1002/cplu.202200085
Abstrakt: Invited for this month's cover is the group of Anna J. McConnell and Christian Näther from Christian-Albrechts-Universität zu Kiel, Germany. The cover picture shows an amidoboronate puzzle divided into four quarters that represent four possible amidoboronates. How do these amidoboronates interconvert? The right combination of aniline (yellow circles) and catechol (grey and purple circles) pieces solves this conundrum and the amidoboronates interconvert via dynamic covalent B-N (left to right) and B-O bonds (top to bottom). More information can be found in the Research Article by Anna J. McConnell and co-workers.
(© 2022 Wiley-VCH GmbH.)
Databáze: MEDLINE
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