The depletion thickness in solutions of semi-flexible polymers near colloidal surfaces: analytical approximations.

Autor: Martens CM; Laboratory of Physical Chemistry, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. m.vis@tue.nl., van Leuken SHM; Laboratory of Physical Chemistry, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. m.vis@tue.nl., Opdam J; Laboratory of Physical Chemistry, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. m.vis@tue.nl., Vis M; Laboratory of Physical Chemistry, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. m.vis@tue.nl.; Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands., Tuinier R; Laboratory of Physical Chemistry, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. m.vis@tue.nl.; Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Jazyk: angličtina
Zdroj: Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2022 Feb 09; Vol. 24 (6), pp. 3618-3631. Date of Electronic Publication: 2022 Feb 09.
DOI: 10.1039/d1cp05026e
Abstrakt: We derive a simple, yet accurate approximate mean-field expression for the depletion thickness δ sf of a solution of dilute semi-flexible polymers next to a hard surface. In the case of a hard wall this equation has the simple form δ sf = δ 0 [1 - tanh( p sf / δ 0 )], where p sf accounts for the degree of flexibility and δ 0 is the depletion thickness in the case of fully flexible polymers. For fixed polymer coil size, increasing the chain stiffness leads to a decrease in the depletion thickness. The approach is also extended to include higher polymer concentrations in the semidilute regime. The analytical expressions are in quantitative agreement with numerical self-consistent field computations. A remarkable finding is that there is a maximum in the depletion thickness as a function of the chain stiffness in the semidilute concentration regime. This also means that depletion attractions between colloidal particles reach a maximum for a certain chain stiffness, which may have important implications for the phase stability of colloid-polymer mixtures. The derived equations could be useful for the description of interactions in- and phase stability of mixtures of colloids and semi-flexible polymers.
Databáze: MEDLINE
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