Broadening the scope of high structural dimensionality nanomaterials using pyridine-based curcuminoids.

Autor: Rodríguez-Cid L; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es., Qian W; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es., Iribarra-Araya J; Department of Chemical Engineering, Biotechnology and Materials, Faculty of Physical and Mathematical Sciences, University of Chile, Beauchef 851, Santiago, 837.0415, Chile. msoler@ing.uchile.cl., Etcheverry-Berríos Á; Department of Chemical Engineering, Biotechnology and Materials, Faculty of Physical and Mathematical Sciences, University of Chile, Beauchef 851, Santiago, 837.0415, Chile. msoler@ing.uchile.cl., Martínez-Olmos E; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es., Choquesillo-Lazarte D; Laboratorio de Estudios Cristalográficos, IACT, CSIC-Universidad de Granada, Avda. de las Palmeras 4, 18100 - Armilla, Granada, Spain., Sañudo EC; Departament de Química Inorgànica i Orgànica, Universitat de Barcelona, C/Martí i Franqués 1-11, 08028 Barcelona, Spain and Institut de Nanociència i Nanotecnologia. Universitat de Barcelona, Av. Diagonal 645, 08028 Barcelona, Spain., Roubeau O; Instituto de Nanociencia y Materiales de Aragón (INMA) CSIC and Universidad de Zaragoza, Plaza San Francisco s/n, 50009 Zaragoza, Spain., López-Periago AM; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es., González-Campo A; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es., Planas JG; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es., Soler M; Department of Chemical Engineering, Biotechnology and Materials, Faculty of Physical and Mathematical Sciences, University of Chile, Beauchef 851, Santiago, 837.0415, Chile. msoler@ing.uchile.cl., Domingo C; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es., Aliaga-Alcalde N; Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus Universitari, 08193 Bellaterra, Spain. nuria.aliaga@icrea.cat conchi@icmab.es and ICREA - Institució Catalana de Recerca i Estudis Avançats, Passeig Lluis Companys 23, 08010 Barcelona, Spain.
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2021 May 25; Vol. 50 (20), pp. 7056-7064.
DOI: 10.1039/d1dt00708d
Abstrakt: We present a new heteroditopic ligand (3pyCCMoid) that contains the typical skeleton of a curcuminoid (CCMoid) decorated with two 3-pyridyl groups. The coordination of 3pyCCMoid with ZnII centres results in a set of novel coordination polymers (CPs) that display different architectures and dimensionalities (from 1D to 3D). Our work analyses how synthetic methods and slight changes in the reaction conditions affect the formation of the final materials. Great efforts have been devoted toward understanding the coordination entities that provide high dimensional systems, with emphasis on the characterization of 2D materials, including analyses of different types of substrates, stability and exfoliation in water. Here, we foresee the great use of CCMoids in the field of CPs and emphasize 3pyCCMoid as a new-born linker.
Databáze: MEDLINE
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