A new heterometallic pivalate {Fe 8 Cd} complex as an example of unusual "ferric wheel" molecular self-assembly.

Autor: Lutsenko IA; N.S.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, GSP-1 119991 Moscow, Russian Federation. irinalu05@rambler.ru., Kiskin MA; N.S.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, GSP-1 119991 Moscow, Russian Federation. irinalu05@rambler.ru., Lysenko KA; Lomonosov Moscow State University, Dept. of Chemistry, Leninskie Gory 1/3, 119991 Moscow, Russian Federation., Zueva EM; Kazan National Research Technolodical University, Karl Marx Str. 68, 420015 Kazan, Russian Federation and Kazan Federal University, Kremlyovskaya Str. 18, 420008 Kazan, Russian Federation., Efimov NN; N.S.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, GSP-1 119991 Moscow, Russian Federation. irinalu05@rambler.ru., Ugolkova EA; N.S.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, GSP-1 119991 Moscow, Russian Federation. irinalu05@rambler.ru., Maksimov YV; N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina Str. 4, 119991Moscow, Russian Federation., Imshennik VK; N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygina Str. 4, 119991Moscow, Russian Federation., Petrova MM; Kazan National Research Technolodical University, Karl Marx Str. 68, 420015 Kazan, Russian Federation., Sidorov AA; N.S.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, GSP-1 119991 Moscow, Russian Federation. irinalu05@rambler.ru., Eremenko IL; N.S.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 31, GSP-1 119991 Moscow, Russian Federation. irinalu05@rambler.ru and Lomonosov Moscow State University, Dept. of Chemistry, Leninskie Gory 1/3, 119991 Moscow, Russian Federation.
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2020 Nov 10; Vol. 49 (43), pp. 15175-15179.
DOI: 10.1039/d0dt03142a
Abstrakt: The interaction of the pivalate complexes of iron(iii), [Fe3O(Piv)6(H2O)3]·HPiv, and cadmium(ii), [Cd(Piv)2], in Et2O resulted in one more type of "ferric wheel" family complex, namely [Fe8(Piv)16{Cd(Piv)2}(μ-OH)8]·Et2O (1). The complex is an octanuclear iron(iii) wheel with a {Cd(Piv)2} moiety asymmetrically incorporated into the ring.
Databáze: MEDLINE
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