Micrometric Monodisperse Solid Foams as Complete Photonic Bandgap Materials.

Autor: Maimouni I; Microfluidique, MEMS et Nanostructures, Institut Pierre-Gilles de Gennes, CNRS UMR 8231, ESPCI Paris and Paris Sciences et Lettres (PSL) Research University, Paris 75005, France., Morvaridi M; Microfluidique, MEMS et Nanostructures, Institut Pierre-Gilles de Gennes, CNRS UMR 8231, ESPCI Paris and Paris Sciences et Lettres (PSL) Research University, Paris 75005, France., Russo M; Microfluidique, MEMS et Nanostructures, Institut Pierre-Gilles de Gennes, CNRS UMR 8231, ESPCI Paris and Paris Sciences et Lettres (PSL) Research University, Paris 75005, France.; Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, PSL University, CNRS, Paris 75005, France., Lui G; Advanced Technology Institute and Department of Physics, University of Surrey, Guildford, Surrey GU2 7XH, United Kingdom., Morozov K; Department of Chemical Engineering Technion, Israel Institute of Technology, Haifa 32000, Israel., Cossy J; Molecular, Macromolecular Chemistry and Materials, ESPCI Paris, PSL University, CNRS, Paris 75005, France., Florescu M; Advanced Technology Institute and Department of Physics, University of Surrey, Guildford, Surrey GU2 7XH, United Kingdom., Labousse M; Gulliver, CNRS UMR 7083, ESPCI Paris and Paris Sciences et Lettres (PSL) Research University, Paris 75005, France., Tabeling P; Microfluidique, MEMS et Nanostructures, Institut Pierre-Gilles de Gennes, CNRS UMR 8231, ESPCI Paris and Paris Sciences et Lettres (PSL) Research University, Paris 75005, France.
Jazyk: angličtina
Zdroj: ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2020 Jul 15; Vol. 12 (28), pp. 32061-32068. Date of Electronic Publication: 2020 Jun 30.
DOI: 10.1021/acsami.0c04031
Abstrakt: Solid foams with micrometric pores are used in different fields (filtering, 3D cell culture, etc.), but today, controlling their foam geometry at the pore level, their internal structure, and the monodispersity, along with their mechanical properties, is still a challenge. Existing attempts to create such foams suffer either from slow speed or size limitations (above 80 μm). In this work, by using a temperature-regulated microfluidic process, 3D solid foams with highly monodisperse open pores (PDI lower than 5%), with sizes ranging from 5 to 400 μm and stiffnesses spanning 2 orders of magnitude, are created for the first time. These features open the way for exciting applications, in cell culture, filtering, optics, etc. Here, the focus is set on photonics. Numerically, these foams are shown to open a 3D complete photonic bandgap, with a critical index of 2.80, thus compatible with the use of rutile TiO 2 . In the field of photonics, such structures represent the first physically realizable self-assembled FCC (face-centered cubic) structure that possesses this functionality.
Databáze: MEDLINE