Polymer Labelling with a Conjugated Polymer-Based Luminescence Probe for Recycling in the Circular Economy.

Autor: Kuřitka I; Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, trida Tomase Bati 5678, 760 01 Zlin, Czech Republic., Sedlařík V; Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, trida Tomase Bati 5678, 760 01 Zlin, Czech Republic., Harea D; Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, trida Tomase Bati 5678, 760 01 Zlin, Czech Republic., Harea E; Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, trida Tomase Bati 5678, 760 01 Zlin, Czech Republic., Urbánek P; Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, trida Tomase Bati 5678, 760 01 Zlin, Czech Republic., Šloufová I; Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030/8, 128 40 Prague, Czech Republic., Coufal R; Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030/8, 128 40 Prague, Czech Republic., Zedník J; Department of Physical and Macromolecular Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030/8, 128 40 Prague, Czech Republic.
Jazyk: angličtina
Zdroj: Polymers [Polymers (Basel)] 2020 May 28; Vol. 12 (6). Date of Electronic Publication: 2020 May 28.
DOI: 10.3390/polym12061226
Abstrakt: In this paper, we present the use of a disubstituted polyacetylene with high thermal stability and quantum yield as a fluorescence label for the identification, tracing, recycling, and eventually anti-counterfeiting applications of thermoplastics. A new method was developed for the dispersion of poly[1-phenyl-2-[p-(trimethylsilyl)phenyl]acetylene] (PTMSDPA) into polymer blends. For such purposes, four representative commodity plastics were selected, i.e., polypropylene, low-density polyethylene, poly(methyl methacrylate), and polylactide. Polymer recycling was mimicked by two reprocessing cycles of the material, which imparted intensive luminescence to the labelled polymer blends when excited by proper illumination. The concentration of the labelling polymer in the matrices was approximately a few tens ppm by weight. Luminescence was visible to the naked eye and survived the simulated recycling successfully. In addition, luminescence emission maxima were correlated with polymer polarity and glass transition temperature, showing a marked blueshift in luminescence emission maxima with the increase in processing temperature and time. This blueshift results from the dispersion of the labelling polymer into the labelled polymer matrix. During processing, the polyacetylene chains disentangled, thereby suppressing their intermolecular interactions. Moreover, shear forces imposed during viscous polymer melt mixing enforced conformational changes, which shortened the average conjugation length of PTMSDPA chain segments. Combined, these two mechanisms shift the luminescence of the probe from a solid- to a more solution-like state. Thus, PTMSDPA can be used as a luminescent probe for dispersion quality, polymer blend homogeneity, and processing history, in addition to the identification, tracing, and recycling of thermoplastics.
Competing Interests: The authors declare no conflict of interest.
Databáze: MEDLINE
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