Bioenergy potential of red macroalgae Gelidium floridanum by pyrolysis: Evaluation of kinetic triplet and thermodynamics parameters.

Autor: Alves JLF; Department of Chemical Engineering and Food Engineering, Federal University of Santa Catarina, 88040-900 Florianópolis, Santa Catarina, Brazil. Electronic address: zeluiz_alves@hotmail.com., Da Silva JCG; Department of Chemical Engineering and Food Engineering, Federal University of Santa Catarina, 88040-900 Florianópolis, Santa Catarina, Brazil. Electronic address: jean.constantino@cear.ufpb.br., da Silva Filho VF; Department of Chemical Engineering and Food Engineering, Federal University of Santa Catarina, 88040-900 Florianópolis, Santa Catarina, Brazil., Alves RF; Department of Materials Science and Engineering, Federal University of Campina Grande, 58429-900 Campina Grande, Paraíba, Brazil., Ahmad MS; School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 30040, China., Ahmad MS; National College of Business Administration and Economics, Punjab, Pakistan., Galdino WVA; Laboratory of Activated Carbon, Department of Chemical Engineering, Federal University of Paraíba, 58033-455 João Pessoa, Paraíba, Brazil., De Sena RF; Laboratory of Activated Carbon, Department of Chemical Engineering, Federal University of Paraíba, 58033-455 João Pessoa, Paraíba, Brazil.
Jazyk: angličtina
Zdroj: Bioresource technology [Bioresour Technol] 2019 Nov; Vol. 291, pp. 121892. Date of Electronic Publication: 2019 Jul 26.
DOI: 10.1016/j.biortech.2019.121892
Abstrakt: The aim of this study was to investigate the bioenergy potential of red macroalgae GF by evaluating its biofuel physicochemical characteristics, and conducting a kinetic study and thermodynamic analysis of pyrolysis for the first time. The thermal decomposition study was performed at low heating rates (5, 10, 20 and 30 °C min -1 ) under N 2 atmosphere. The thermal behavior of GF pyrolysis indicated the presence of three different decomposition stages, which are associated with different components in its structure and consequently influence the kinetic and thermodynamic parameters. The kinetic triplet obtained for GF provided a suitable description of experimental thermal behavior. The thermodynamic parameters demonstrated that GF is as a new promising feedstock for bioenergy and presented a similar potential to well-known bioenergy feedstock.
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Databáze: MEDLINE