NMR-based and chemometric approaches applicable to adulteration studies for assessment of the botanical origin of edible oils.

Autor: Ravaglia LM; Instituto de Química, Universidade Federal de Mato Grosso do Sul, Av. Filinto Müller, 1555, CP 549, Campo Grande, MS 79074-460 Brazil., Pizzotti ABC; Instituto de Química, Universidade Federal de Mato Grosso do Sul, Av. Filinto Müller, 1555, CP 549, Campo Grande, MS 79074-460 Brazil., Alcantara GB; Instituto de Química, Universidade Federal de Mato Grosso do Sul, Av. Filinto Müller, 1555, CP 549, Campo Grande, MS 79074-460 Brazil.
Jazyk: angličtina
Zdroj: Journal of food science and technology [J Food Sci Technol] 2019 Jan; Vol. 56 (1), pp. 507-511. Date of Electronic Publication: 2018 Dec 04.
DOI: 10.1007/s13197-018-3485-3
Abstrakt: The health benefits of edible oils, especially promoted by ω3 and ω9 fatty acids, have been associated with their botanical origin. In order to investigate fatty acid profiles, we assessed Brazil nut, chia, linseed, sesame (toasted and raw), and soybean oils by 1 H nuclear magnetic resonance ( 1 H NMR) and chemometrics. PCA plots revealed important relationships between chemical composition and botanical origin for reference and commercial samples. Strong evidence of commercial Brazil nut oil adulteration was confirmed using a spiking procedure. Our findings show that NMR and chemometrics are successful tools for correlating fatty acid profile with botanical origin, which can be suitable for detecting sample adulteration.
Databáze: MEDLINE