| Autor: |
Reiné P; Department of Organic Chemistry, Faculty of Science, Universidad de Granada (UGR), E-18071 Granada, Spain. jmcuerva@ugr.es., Ortuño AM, Resa S, Álvarez de Cienfuegos L, Blanco V, Ruedas-Rama MJ, Mazzeo G, Abbate S, Lucotti A, Tommasini M, Guisán-Ceinos S, Ribagorda M, Campaña AG, Mota A, Longhi G, Miguel D, Cuerva JM |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 Dec 11; Vol. 54 (99), pp. 13985-13988. |
| DOI: |
10.1039/c8cc08395a |
| Abstrakt: |
Here we describe a new class of CPL switches based on oxophilic interactions between chiral sulfoxide-containing ortho-phenylene ethynylene (o-OPE) foldamers and cationic metals. These systems represent a unique case combining high glum values (up to 0.7 × 10-2) and high quantum yields in both folded ON and unfolded OFF CPL states. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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