Starch-Flavor Complexation Applied to 2-Acetyl-1-pyrroline.

Autor: Hausch BJ; Univerity of Illinois at Urbana-Champaign , Department of Food Science and Human Nutrition , 1302 West Pennsylvania Avenue , Urbana , Illinois 61801 , United States., Little JA; Functional Food Research Unit, United States Department of Agriculture, Agricultural Research Service , National Center for Agricultural Utilization Research , 1815 North University Street , Peoria , Illinois 61604 , United States., Kenar JA; Functional Food Research Unit, United States Department of Agriculture, Agricultural Research Service , National Center for Agricultural Utilization Research , 1815 North University Street , Peoria , Illinois 61604 , United States., Cadwallader KR; Univerity of Illinois at Urbana-Champaign , Department of Food Science and Human Nutrition , 1302 West Pennsylvania Avenue , Urbana , Illinois 61801 , United States.
Jazyk: angličtina
Zdroj: Journal of agricultural and food chemistry [J Agric Food Chem] 2018 Nov 07; Vol. 66 (44), pp. 11718-11728. Date of Electronic Publication: 2018 Oct 29.
DOI: 10.1021/acs.jafc.8b04133
Abstrakt: The pleasant popcorn-like smelling compound 2-acetyl-1-pyrroline (2AP) occurs naturally in many foods but is scarcely used as a flavoring agent due to its great instability. In this work, we evaluate the potential of high amylose corn starch to complex and stabilize 2AP. The methodology was first optimized using model compounds, 2-acetylpyridine and 2-acetyl-2-thiazoline, and then applied to 2AP. Complexes were successfully prepared and characterized using X-ray diffraction, gas chromatography, and differential scanning calorimetry. Loadings of up to 0.504 (±0.071)% 2AP were achieved, and storage studies showed that over half of the flavor was retained after 2 weeks at 0% relative humidity. To our knowledge, this is the first demonstration that 2AP can form amylose inclusion complexes and may lead to a method to effectively stabilize this labile aroma compound.
Databáze: MEDLINE