| Autor: |
Jadhav SB; Department of Organic Synthesis & Process Chemistry, CSIR-Indian Institute of Chemical Technology (CSIR-IICT), Hyderabad 500007, India. rchegondi@iict.res.in cramhcu@gmail.com., Thopate SB, Nanubolu JB, Chegondi R |
| Jazyk: |
angličtina |
| Zdroj: |
Organic & biomolecular chemistry [Org Biomol Chem] 2019 Feb 13; Vol. 17 (7), pp. 1937-1946. |
| DOI: |
10.1039/c8ob02284d |
| Abstrakt: |
The rhodium-catalyzed arylative cyclization of enone tethered-cyclohexadienones has been developed with high efficiency, thus providing cis-fused bicyclic enones in good yields and with excellent diastereoselectivities. Furthermore, this mild transformation has a broad range of substrate scope and excellent functional group tolerance. In addition, bicyclic products have an enone functionality, which can be a synthetically valuable handle for further transformations. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
