Characterization of smokeless powders using multiplexed collision-induced dissociation mass spectrometry and chemometric procedures.

Autor: Reese KL; Forensic Science Program, School of Criminal Justice, Michigan State University, East Lansing, MI 48824, United States; Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States., Jones AD; Department of Chemistry, Michigan State University, East Lansing, MI 48824, United States; Department of Biochemistry and Molecular Biology, Michigan State University, East Lansing, MI 48824, United States., Smith RW; Forensic Science Program, School of Criminal Justice, Michigan State University, East Lansing, MI 48824, United States. Electronic address: rwsmith@msu.edu.
Jazyk: angličtina
Zdroj: Forensic science international [Forensic Sci Int] 2017 Mar; Vol. 272, pp. 16-27. Date of Electronic Publication: 2016 Dec 21.
DOI: 10.1016/j.forsciint.2016.12.021
Abstrakt: This work demonstrates a non-targeted mass spectrometry approach for identification of organic compounds in smokeless powders. Unburned powders were removed from various commercial ammunitions of different brand, primer composition, caliber, and age. The unburned powders and corresponding fired residues were analyzed by liquid chromatography-atmospheric pressure chemical ionization-time-of-flight mass spectrometry (LC-APCI-TOFMS). Multiplexed collision-induced dissociation was performed at increasing collision potentials resulting in successive fragmentation that provided structural information for compound identification in a non-targeted manner. Nine compounds were identified in the powders, including akardite II, ethyl centralite, diphenylamine, N-nitrosodiphenylamine, and dibutyl phthalate. Multivariate statistical procedures were performed to first investigate association and discrimination of the unburned powders. Principal components analysis (PCA) of the chemical profiles suggested nine distinct groups of powders, according to the dominant organic compounds present. The clusters formed in hierarchical cluster analysis (HCA) were mostly in agreement with PCA groupings although HCA provided a metric to quantify the similarity. Finally, association of the fired residue to the corresponding unburned powder was possible although the success was highly dependent on the composition of the unburned powder and the extent of compound depletion as a result of firing.
(Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.)
Databáze: MEDLINE
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