| Autor: |
Anderson BJ; Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA., Freedman MB; Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA., Millikan SP; Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA., Smolenski VA; Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA., Jasinski JP; Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA. |
| Abstrakt: |
In the title compound, C16H16N4OS, an intra-molecular C-H⋯S hydrogen bond is observed. With the exception of the phenyl ring of the phenyl-propyl-idene unit, the remainder of the mol-ecule has an almost planar skeleton with an r.m.s. deviation of 0.121 (5) Å from the plane through the remaining 16 atoms. In the crystal O-H⋯N hydrogen bonds are observed between the terminal hy-droxy-imino groups, forming inverson dimers with R 2 (2)(6) graph-set motifs. Additional C-H⋯N contacts stack the dimers along [100]. While no π-π inter-actions are present, weak C-H⋯O and O-H⋯Cg inter-actions are also observed and help stabilize the crystal packing. |
