Crystal structure of bis-(prop-2-yn-1-yl) 5-nitro-isophthalate.

Autor: Ezhilarasi KS; PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India., Selvarani S; Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai-25, India., Rajakumar P; Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai-25, India., Revathi BK; PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India., Usha G; PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 May 30; Vol. 71 (Pt 6), pp. o435. Date of Electronic Publication: 2015 May 30 (Print Publication: 2015).
DOI: 10.1107/S2056989015009846
Abstrakt: The whole mol-ecule of the title compound, C14H9NO6, is generated by twofold rotation symmetry; the twofold axis bis-ects the nitro group and the benzene ring. The nitro group is inclined to the benzene ring by 14.42 (9)°. The prop-2-yn-1-yl groups are inclined to the benzene ring by 13 (2)° and to each other by 24 (3)°; one directed above the plane of the benzene ring and the other below. In the crystal, mol-ecules are linked via pairs of C-H⋯O hydrogen bonds, forming inversion dimers with an R 2 (2)(18) ring motif. The dimers are linked by further C-H⋯O hydrogen bonds, forming sheets lying parallel to (100).
Databáze: MEDLINE