| Autor: |
Stieber SC; CaRLa (Catalysis Research Laboratory), Im Neuenheimer Feld 584, 69120 Heidelberg, Germany., Huguet N, Kageyama T, Jevtovikj I, Ariyananda P, Gordillo A, Schunk SA, Rominger F, Hofmann P, Limbach M |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Jul 11; Vol. 51 (54), pp. 10907-9. |
| DOI: |
10.1039/c5cc01932j |
| Abstrakt: |
We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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