| Autor: |
Suthagar K; Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand. antony.fairbanks@canterbury.ac.nz., Polson MI, Fairbanks AJ |
| Jazyk: |
angličtina |
| Zdroj: |
Organic & biomolecular chemistry [Org Biomol Chem] 2015 Jun 21; Vol. 13 (23), pp. 6573-9. Date of Electronic Publication: 2015 May 18. |
| DOI: |
10.1039/c5ob00851d |
| Abstrakt: |
De-protected arabino N-glycosyl sulfamides, sulfonamides and sulfamates were found to mutarotate and convert from the furanose to the thermodynamically more stable pyranose form in aqueous solution. The presence of a strongly electron withdrawing group in the alkyl chain stopped mutarotation and furanose/pyranose equilibration, allowing the isolation of the first unprotected furanose N-glycosyl sulfonamide. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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