| Autor: |
Baum AE; Department of Chemistry, Marquette University , 535 North 14th Street, Milwaukee, Wisconsin 53233, United States., Park H, Lindeman SV, Fiedler AT |
| Jazyk: |
angličtina |
| Zdroj: |
Inorganic chemistry [Inorg Chem] 2014 Dec 01; Vol. 53 (23), pp. 12240-2. Date of Electronic Publication: 2014 Nov 13. |
| DOI: |
10.1021/ic502564r |
| Abstrakt: |
Two mononuclear iron(II) p-semiquinonate (pSQ) complexes have been generated via one-electron reduction of precursor complexes containing a substituted 1,4-naphthoquinone ligand. Detailed spectroscopic and computational analysis confirmed the presence of a coordinated pSQ radical ferromagnetically coupled to the high-spin Fe(II) center. The complexes are intended to model electronic interactions between (semi)quinone and iron cofactors in biology. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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