Organocatalytic diimide reduction of enamides in water.

Autor: Marsh BJ; Department of Chemistry, University of Bath, Bath, BA2 7AY, UK., Heath EL, Carbery DR
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Jan 07; Vol. 47 (1), pp. 280-2. Date of Electronic Publication: 2010 Aug 16.
DOI: 10.1039/c0cc02272a
Abstrakt: Bridged flavinium organocatalysts have displayed efficacy in the diimide mediated reduction of enamides in aqueous conditions. This represents the first diimide reduction of an electron rich alkene and offers a clean alternative to the use of alkylating agents for N-alkylation.
Databáze: MEDLINE