Rearrangement of pyrrolines derived from the Birch reduction of electron-deficient pyrroles: radical ring-expansion to substituted tetrahydropyridines.

Autor: Turner PG; Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UKOX1 3TA., Donohoe TJ, Cousins RP
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Jun 21 (12), pp. 1422-3. Date of Electronic Publication: 2004 May 18.
DOI: 10.1039/b404002c
Abstrakt: Access to the synthetically important tetrahydropyridine motif has been achieved by radical rearrangement of pyrrolines obtained from the Birch reduction of electron-deficient pyrroles.
Databáze: MEDLINE