| Autor: |
Kashimura S; Faculty of Science and Technology, Kinki University, 3-4-1 Kowakae Higashi-Osaka 577, Japan., Ishifune M, Yamashita N, Bu HB, Takebayashi M, Kitajima S, Yoshiwara D, Kataoka Y, Nishida R, Kawasaki Si, Murase H, Shono T |
| Jazyk: |
angličtina |
| Zdroj: |
The Journal of organic chemistry [J Org Chem] 1999 Sep 03; Vol. 64 (18), pp. 6615-6621. |
| DOI: |
10.1021/jo990180z |
| Abstrakt: |
The electroreduction of alkylaryldichlorosilane carried out with Mg cathode and anode in a single compartment cell gave high molecular weight poly(alkylarylsilane) (M(n) = 5200-31000, M(w)/M(n) = 1.4-1.8) in 5-79% yield. The effects of electrode material, monomer concentration, amount of supplied electricity, and ultrasound were investigated. This electroreductive method was also successfully applied to the synthesis of polygermanes, silane-geramane copolymers, and also poly[p-(disilanylene)phenylenes]. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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