Tetrathiafulvalene-Based Materials for Organic Field Effect Transistors. Inspection of Their Semiconductor Properties by Means of Molecular Spectroscopy and Quantum Chemistry

Autor: Marta Mas-Torrent, Marek Z. Zgierski, Juan Casado, Concepció Rovira, Juan T. López Navarrete, Mari Carmen Ruiz Delgado

Publikováno v: The Journal of Physical Chemistry C. 111:10110-10118

The absorption and emission electronic and vibrational Raman spectra of a series of tetrathiafulvalene compounds have been recorded, assigned with the guide of density functional theory calculations, and interpreted according to their chemical nature

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d23f8e531a80a0d1096895458e751472
https://doi.org/10.1021/jp073148e

Crystal structure of tetramethyltetrathiafulvalenium (1S)-camphor-10-sulfonate dihydrate

Autor: Magali Allain, Flavia Pop, Michel Giffard, Cécile Mézière, Mathieu Sommer

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 7, Pp 748-751 (2015)
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Structure Reports
Acta Crystallographica Section E: Structure Reports Online, International Union of Crystallography, 2015, E71, pp.748-751. ⟨10.1107/S2056989015010294⟩

In this salt, two types of TMTTF units are present as TMTTF. + radical cations which form one-dimensional stacks in which they are associated two by two, forming dimers with short S⋯S contacts. The S-camphSO3 anions also form stacks and are connect

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::260de4a11c8cb9f9a7c6dfe6c22319d7
https://doi.org/10.1107/s2056989015010294

Conducting and Magnetic Organometallic Molecular Materials

Autor: Marc Fourmigué, Lahcène Ouahab

For several years, the two parallel worlds of Molecular Conductors in one hand and Molecular Magnetism in the other have grown side by side, the former essentially based on radical organic molecules, the latter essentially based on the high spin prop