Tuning Lanthanide Reactivity Towards Small Molecules with Electron-Rich Siloxide Ligands.

Autor: Andrez, Julie¹, Pécaut, Jacques¹, Bayle, Pierre ‐ Alain¹, Mazzanti, Marinella² marinella.mazzanti@epfl.ch

Publikováno v: Angewandte Chemie. Sep2014, Vol. 126 Issue 39, p10616-10620. 5p.

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The Influence of Alkali Metal Ions on the Stability and Reactivity of Chromium(III) Superoxide Moieties Spanned by Siloxide Ligands

Autor: Christian Herwig, Christian Limberg, Santina Hoof, Beatrice Braun-Cula, Marie-Louise Wind

Publikováno v: Chemistry – A European Journal. 25:5743-5750

In recent years, it has become clear that the presence of redox-inactive Lewis acidic metal ions can decisively influence the reactivity of metal-dioxygen moieties that are formed in the course of O2 activation, in molecular complexes, and metalloenz

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e365e4210eca7bba3f329230db3c0631
https://doi.org/10.1002/chem.201900236

Tuning Lanthanide Reactivity Towards Small Molecules with Electron-Rich Siloxide Ligands

Autor: Pierre-Alain Bayle, Marinella Mazzanti, Jacques Pécaut, Julie Andrez

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2014, 53 (39), pp.10448-10452. ⟨10.1002/anie.201405031⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2014, 53 (39), pp.10448-10452. ⟨10.1002/anie.201405031⟩

The synthesis, structure, and reactivity of stable homoleptic heterometallic LnL(4)K(2) complexes of divalent lanthanide ions with electron-rich tris(tert-butoxy)siloxide ligands are reported. The [Ln(OSi(OtBu)(3))(4)K-2] complexes (Ln=Eu, Yb) are st

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a18f9ca05e76854078226d8f1754da6a
https://hal.science/hal-01979870

Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

Autor: Marta Falcone, Luciano Barluzzi, Marinella Mazzanti

Publikováno v: Chemical communications (Cambridge, England). 55(87)

The synthesis and reactivity of uranium compounds supported by the tris-tert-butoxysiloxide ligand is surveyed. The multiple binding modes of the tert-butoxysiloxide ligand have proven very well suited to stabilize highly reactive homo- and heteropol

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e928c70f24f419353af85dc97253e615
https://pubmed.ncbi.nlm.nih.gov/31608910