Group (IV) Metallocene Complexes with Bulky ω-aryloxyalkyl-Substituted Indenyl Ligands as Catalyst Precursors for Homogeneous Ethylene Polymerization

Autor: Khalil Ahmad, Helmut Guido Alt

Publikováno v: Iranian Journal of Chemistry & Chemical Engineering, Vol 37, Iss 2, Pp 85-94 (2018)

A series of seven new complexes of zirconium and hafnium with bulky ω-aryloxyalkyl substituted indenyl ligands were synthesized and characterized by NMR spectroscopy and elemental analysis. These complexes were activated with methylaluminoxane and t

Externí odkaz: https://doaj.org/article/6fd32ad97cdc49c3b9fe57436943e4a5

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Exploring the Organometallic Route to Molecular Spin Qubits: The [CpTi(cot)] Case

Autor: Luana C de Camargo, Enrico Salvadori, Giovana G. Nunes, Jaísa F. Soares, Lorenzo Sorace, Matteo Briganti, Francielli S. Santana, Ronny R. Ribeiro, Roberta Sessoli, Federico Totti, Stefano Benci, Mario Chiesa, Danilo Stinghen, Renato Torre

Publikováno v: Angewandte Chemie (Int. ed., Print) 60 (2021): 2588–2593. doi:10.1002/anie.202009634
info:cnr-pdr/source/autori:de Camargo L.C.; Briganti M.; Santana F.S.; Stinghen D.; Ribeiro R.R.; Nunes G.G.; Soares J.F.; Salvadori E.; Chiesa M.; Benci S.; Torre R.; Sorace L.; Totti F.; Sessoli R./titolo:Exploring the Organometallic Route to Molecular Spin Qubits: The [CpTi(cot)] Case/doi:10.1002%2Fanie.202009634/rivista:Angewandte Chemie (Int. ed., Print)/anno:2021/pagina_da:2588/pagina_a:2593/intervallo_pagine:2588–2593/volume:60
Angewandte Chemie International Edition

The coherence time of the 17-electron, mixed sandwich complex [CpTi(cot)], (η8 -cyclooctatetraene)(η5 -cyclopentadienyl)titanium, reaches 34 μs at 4.5 K in a frozen deuterated toluene solution. This is a remarkable coherence time for a highly prot

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::12069d2511462113dc7e25f33ed8584f
https://zenodo.org/record/4926051

Development of novel photoactive cationic zirconocene complexes

Autor: Dunlop, David

Title: Development of novel photoactive cationic zirconocene complexes Author: Bc. David Dunlop Department: Department of inorganic chemistry Supervisor: RNDr. Martin Lamač Ph.D. Advisor: prof. RNDr. Petr Štěpnička, Ph.D., DSc. Abstract: Environm

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od______2186::d57c049c08a406e4669ba5410f4e9173
http://www.nusl.cz/ntk/nusl-452440

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