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Channel Confinement of Aromatic Petrochemicals via Aryl–Perfluoroaryl Interactions With a B←N Host

Autor: Herbert Höpfl, Michael A. Sinnwell, Hugo Morales-Rojas, Megan M. D'mello, Gonzalo Campillo-Alvarado, Leonard R. MacGillivray

Publikováno v: Frontiers in Chemistry, Vol 7 (2019)
Frontiers in Chemistry

We report channel confinement properties of an electron-deficient boron host derived from the orthogonal B←N interaction between a boronic ester and trans-pentafluorostilbazole. The boron host forms one-dimensional channels in the crystalline solid

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6a737671e0a82c3fb65da862313b9049
https://doi.org/10.3389/fchem.2019.00695

A simple polarimetry technique for predicting the absolute configuration of the preferred enantiomer in chiral host-guest inclusion complexes

Autor: Benita Barton, Pieter L. Pohl

Publikováno v: South African Journal of Chemistry; Vol 68 (2015); 215-218
South African Journal of Chemistry, Volume: 68, Pages: 215-218, Published: 2015

Amethod for predicting the configuration of the preferred guest enantiomer in an inclusion complex with an optically pure host compound was developed. The method involves simply measuring the optical rotation of the host-guest inclusion complex as a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1aacc314d0e08ee91ac54f1b54bf98c3
https://doi.org/10.17159/0379-4350/2015/v68a29

Inclusion Complexes Between Polytetrahydrofuran-b-Amylose Block Copolymers and Polytetrahydrofuran Chains

Publikováno v: Macromolecular Bioscience. 15(6):812-828

Amylose inclusion complexes are prepared by complexation of synthetic amylose having a covalently attached PTHF block (PTHF-b-amylose) with guest polytetrahydrofuran of molecular weights of 650 and 1000 g · mol−1 (PTHF650 and PTHF1000). Differenti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dris___00893::efad99788622af3135192868cb9ac558
https://doi.org/10.1002/mabi.201400515

Tunable Properties of Inclusion Complexes Between Amylose and Polytetrahydrofuran

Publikováno v: Macromolecular Bioscience. 13(6):767-776

Amylose and polytetrahydrofuran (PTHF) are mixed in an aqueous solution to form inclusion complexes. DSC shows that immediate mixing results in complexes having lower melting temperatures compared with complexes prepared with longer mixing times. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dris___00893::a248ae4e7dc41839a21c952c30244f6d
https://hdl.handle.net/11370/61ff41a5-4ca3-456f-a929-f3f84d62c530