Zobrazeno 1 - 10 of 690 pro vyhledávání: '"hydride ligands"'
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Akademický článek
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2
Coordination of the Hemilabile Ligand Diphenylvinylphosphine to Ru4(µ-H)4(CO)12: Synthesis, Stability and Structural Studies
Autor: Zhen Xuan Wong, Han Wee Ong, Ren Kai Edward Neo, Rakesh Ganguly, Yong Leng Kelvin Tan, Elumalai Kumaran, Weng Kee Leong
Publikováno v: Journal of Cluster Science. 33:2337-2343
The tetraruthenium tetrahydrido carbonyl cluster Ru4(µ-H)4(CO)12 (1) reacts with diphenylvinylphosphine under thermal activation to give the substitution products Ru4(µ-H)4(CO)12−n(κ1-Ph2PCH=CH2)n, (2) (n = 3 (a); 4 (b)). Both 2a and 2b have bee
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a84a71eb0f87e1d4cb802392f5d6a3f5
https://doi.org/10.1007/s10876-021-02150-0
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3
Synthesis, Characterization, and Reactivity of a Hydrido‐ and Imido‐Bridged Dinuclear Ytterbium(III) Complex
Autor: Qingqing Wen, Thayalan Rajeshkumar, Laurent Maron, Xuebing Leng, Yaofeng Chen
Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2022, 61 (25), ⟨10.1002/anie.202200540⟩
International audience; The trivalent rare-earth metal hydrido and imido complexes are of versatile reactivity, and many such complexes have been synthesized. However, no example of a rare-earth metal complex bearing both hydrido- and imido-ligands h
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::45d096e91d376707b4011d0977649c34
https://doi.org/10.1002/ange.202200540
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4
Bifunctional W/NH Cuboidal Aminophosphino W3S4 Cluster Hydrides: The Puzzling Behaviour behind the Hydridic-Protonic Interplay
Autor: Eva Guillamón, Rosa Llusar, Andrés G. Algarra, Tomás F. Beltrán, Jose Ángel Pino-Chamorro, Carmen E. Castillo, M. Jesús Fernández-Trujillo, Elena Pedrajas, Manuel G. Basallote, Vicent S. Safont
Publikováno v: Repositori Universitat Jaume I
Universitat Jaume I
The novel [W3S4H3(edpp)3]+ (edpp=(2-aminoethyl)diphenylphosphine) (1+) cluster hydride with an acidic −NH2 functionality has been synthetized and studied. Its crystal structure shows the characteristic incomplete W3S4 cubane core with the outer pos
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6
Synthesis of heteroleptic gallium-substituted antimony hydrides by stepwise β-H elimination
Autor: Christoph Wölper, Christoph Helling, Stephan Schulz
Publikováno v: Dalton Transactions. 49:11835-11842
Heteroleptic stibanes Cp*(R)SbCl (R = Dip 1, N(SiMe3)22, OB(NDipCH)23; Cp* = C5Me5; Dip = 2,6-i-Pr2-C6H3) react with monovalent gallanediyl LGa (L = HC[C(Me)N(Dip)]2) with elimination of 1,2,3,4-tetramethylfulvene, yielding heteroleptic metal-stabili
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7c71987d5eafbee958bde3a74ca7f9d5
https://doi.org/10.1039/d0dt01937b
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7
Trans Influence of Boryl Ligands in CO2 Hydrogenation on Ruthenium Complexes: Theoretical Prediction of Highly Active Catalysts for CO2 Reduction
Autor: Zhuhong Yang, Zhangyong Liu, Jun Li, Tian Liu, Lipeng Tang
Publikováno v: Catalysts, Vol 11, Iss 1356, p 1356 (2021)
Catalysts
Volume 11
Issue 11
In this work, we study the trans influence of boryl ligands and other commonly used non-boryl ligands in order to search for a more active catalyst than the ruthenium dihydride complex Ru(PNP)(CO)H2 for the hydrogenation of CO2. The theoretical calcu
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::13af627ba0530be7f158d7f89f43416e
https://www.mdpi.com/2073-4344/11/11/1356
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8
Akademický článek
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10
Evaluation of attractive interactions in the second coordination sphere of iron complexes containing pendant amines
Autor: R. Morris Bullock, Tianbiao Liu, Qian Liao, Christina M. Klug, Samantha I. Johnson, Eric S. Wiedner, Daniel L. DuBois
Publikováno v: Dalton Transactions. 48:4867-4878
The interactions between pendant amines in the second coordination sphere and ligands in the first coordination sphere are important for understanding the structures and reactivity of complexes containing PR2NR'2 ligands, which have been shown to be
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8da88ef82c529ab5f20dee32650e1463
https://doi.org/10.1039/c9dt00708c
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