Zobrazeno 1 - 10
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pro vyhledávání: '"dialkyl α-hydroxyphosphonates"'
Publikováno v:
Molecules, Vol 25, Iss 17, p 3793 (2020)
The two-step acidic hydrolysis of α-hydroxybenzylphosphonates and a few related derivatives was monitored in order to determine the kinetics and to map the reactivity of the differently substituted phosphonates in hydrolysis. Electron-withdrawing su
Externí odkaz:
https://doaj.org/article/1982bb6ae4fa49e995902e6301de8508
Publikováno v:
Journal of the American Chemical Society. 76:4186-4187
Publikováno v:
Molecules
Volume 25
Issue 17
Molecules, Vol 25, Iss 3793, p 3793 (2020)
Volume 25
Issue 17
Molecules, Vol 25, Iss 3793, p 3793 (2020)
The two-step acidic hydrolysis of &alpha
hydroxybenzylphosphonates and a few related derivatives was monitored in order to determine the kinetics and to map the reactivity of the differently substituted phosphonates in hydrolysis. Electron-withd
hydroxybenzylphosphonates and a few related derivatives was monitored in order to determine the kinetics and to map the reactivity of the differently substituted phosphonates in hydrolysis. Electron-withd
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Akademický článek
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Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements; April 1995, Vol. 101 Issue: 1 p17-27, 11p
Publikováno v:
Phosphorus, Sulfur & Silicon & the Related Elements; 2017, Vol. 192 Issue 6, p752-757, 6p
Autor:
Wolfgang H.G. Laux, Chris Meier
Publikováno v:
Tetrahedron: Asymmetry. 6:1089-1092
A highly enantioselective synthesis of dialkyl α-hydroxyphosphonates achieved by a oxazaborolidine catalyzed reduction with catecholborane starting with α-ketophosphonates is described. Both α-aryl- and α-alkylketophosphonates were reduced using
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 101:17-27
5-Methylisatin ( 1b) reacts with TAP ( 4a–c) and/or DAP ( 3a-c) to give the respective dialkyl α-hydroxyphosphonates (8a-c). Isatin-monoxime ( 5a) and 5-methyl isatin-monoxime ( 5b) react with alkyl phosphites to give dialkyl 2-oxo-indolyl phospho
Autor:
Chris Meier, Wolfgang H.G. Laux
Publikováno v:
ChemInform. 26
A highly enantioselective synthesis of dialkyl α-hydroxyphosphonates achieved by a oxazaborolidine catalyzed reduction with catecholborane starting with α-ketophosphonates is described. Both α-aryl- and α-alkylketophosphonates were reduced using