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Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 11, Pp 1657-1663 (2019)
The reactions of N-heterocyclic carbene CuI and AgI halides with potassium thio- or selenocyanate gave unexpected products. The attempted substitution reaction of bromido(1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene)silver (NHC*—Ag—Br) with KSCN y
Externí odkaz:
https://doaj.org/article/9a435472bac34094a56d9eb31c15c3b8
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 11, Pp 1657-1663 (2019)
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 11, Pp 1657-1663 (2019)
This article reports the unexpected reactions of Cu and Ag NHC bromides with potassium thio- or selenocyanates. It contains the first report of the boomerang-shaped [Ag(SCN)3]2− ion.
The reactions of N-heterocyclic carbene CuI and AgI halide
The reactions of N-heterocyclic carbene CuI and AgI halide
Kniha
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Autor:
Tacke M; School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland., Marhöfer D; School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland., Althani H; School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland., Müller-Bunz H; School of Chemistry, University College Dublin, Belfield, Dublin 4, Ireland.
Publikováno v:
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2019 Oct 22; Vol. 75 (Pt 11), pp. 1657-1663. Date of Electronic Publication: 2019 Oct 22 (Print Publication: 2019).