Zobrazeno 1 - 10
of 639
pro vyhledávání: '"backbonding"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 2, Pp 304-307 (2019)
Structural characterization of the ionic title complex, [MgBr(THF)5][Co(dpbz)2]·2THF [THF is tetrahydrofuran, C4H8O; dpbz is 1,2-bis(diphenylphosphanyl)benzene, C30H24P2], revealed a well-separated cation and anion co-crystallized with two THF solve
Externí odkaz:
https://doaj.org/article/97541b00201d4fefa5f85d1ffec3ef1f
Akademický článek
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Autor:
Tiemann, Matthew Austin
Carbene ligands over these years have become a heavily utilizes and effective ligand for catalysis. The diamino carbene class of ligands are slightly less understood. The effects of bis(carbene) ligand structures of palladium (II) catalysts were inve
Externí odkaz:
https://digital.library.unt.edu/ark:/67531/metadc2179238/
Publikováno v:
Chemistry – A European Journal. 27:17849-17861
A case study on the effect of the employment of two different NHC ligands in complexes [Ni(NHC)2 ] (NHC=i Pr2 ImMe 1Me , Mes2 Im 2) and their behavior towards alkynes is reported. The reaction of a mixture of [Ni2 (i Pr2 ImMe )4 (μ-(η2 : η2 )-COD)
Akademický článek
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Autor:
Michael L. Tarlton, Jochen Autschbach, Justin R. Walensky, Xiaojuan Yu, Steven P. Kelley, Robert J. Ward
Publikováno v:
Chemistry – A European Journal. 27:14396-14400
The coordination of tBuNC and CO with the diarsenido complexes (C5 Me5 )2 An(η2 -As2 Mes2 ), An=Th, U, has been investigated. For the first time, a comparison between isostructural complexes of ThIV and UIV has been possible with CO; density functio
Publikováno v:
The Journal of Physical Chemistry A. 125:7956-7966
The nature of donor-acceptor interactions is important for the understanding of dative bonding and can provide vital insights into many chemical processes. Here, we have performed a computational study to elucidate substantial differences between dif
Publikováno v:
The Journal of Physical Chemistry A. 125:7207-7216
A theoretical analysis of reductive coupling of isocyanide and CO mediated by a Cr-Cr quintuple bonded complex and B-B multiple bonded complexes shows how the difference in donor-acceptor capability of isocyanide and CO ligands controls the product d
Autor:
Rubio Rueda, Julieta Andrea
ilustraciones, fotografías, graficas El etanol es un alcohol primario obtenido tanto por vía petroquímica como a partir de biomasa. Entre los derivados más importantes que se obtienen del etanol se encuentra el n-butanol, que se utiliza principal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1326::16e215e59aad00c9211e6de6b49157e0
https://repositorio.unal.edu.co/handle/unal/83928
https://repositorio.unal.edu.co/handle/unal/83928
Autor:
Ralf Tonner, Carsten Jenne, Sebastian Kawa, Martin Mayer, Knut R. Asmis, Harald Knorke, Jonas Warneke, Francine Horn, Markus Rohdenburg
Publikováno v:
Chemistry – A European Journal. 27:10274-10281
Electrophilic anions of type [B12 X11 ]- posses a vacant positive boron binding site within the anion. In a comparatitve experimental and theoretical study, the reactivity of [B12 X11 ]- with X=F, Cl, Br, I, CN is characterized towards different nucl