Na3MgB37Si9: an icosahedral B12 cluster framework containing {Si8} units

Autor: Haruhiko Morito, Takuji Ikeda, Yukari Katsura, Hisanori Yamane

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 2, Pp 203-206 (2022)

Single crystals of a novel sodium–magnesium boride silicide, Na3MgB37Si9 [a = 10.1630 (3) Å, c = 16.5742 (6) Å, space group R\overline{3}m (No. 166)], were synthesized by heating a mixture of Na, Si and crystalline B with B2O3 flux in Mg vapor at

Externí odkaz: https://doaj.org/article/43b70feae2014186a9f59008a97792ac

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Na 3 MgB 37 Si 9 : an icosa-hedral B 12 cluster framework containing {Si 8 } units.

Autor: Morito H; Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan., Ikeda T; Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology, 4-2-1, Nigatake, Miyagino-ku, Sendai 983-8551, Japan., Katsura Y; National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki, 305-0047, Japan., Yamane H; Institute of Multidisciplinary Research for Advanced Materials, Tohoku, University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan.

Publikováno v: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2022 Jan 18; Vol. 78 (Pt 2), pp. 203-206. Date of Electronic Publication: 2022 Jan 18 (Print Publication: 2022).