Zobrazeno 1 - 4
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pro vyhledávání: '"b and Arnold L. Rheingold"'
Autor:
a T. Suren Lewkebandara, a Charles H. Winter, a Peggy J. McKarns, b Glenn P. A. Yap, b Louise M. Liable-Sands, b and Arnold L. Rheingold
Publikováno v:
Inorganic Chemistry. 37:418-424
Treatment of titanium tetrachloride (2 equiv) with dimethyl diselenide or diethyl diselenide (1 equiv) in hexane at 0 degrees C, followed by crystallization at -20 degrees C, afforded (TiCl(4))(2)(Se(2)(CH(3))(2)) (78%) and (TiCl(4))(2)(Se(2)(CH(2)CH
Autor:
b and Arnold L. Rheingold, a Michael Blumenstein, a Sunita Saluja, b Glenn P. A. Yap, a Lynn C. Francesconi, a Yong Yong Zheng
Publikováno v:
Inorganic Chemistry. 35:6656-6666
Three methods have been developed to prepare gallium and indium complexes of three tetradentate N(2)S(2) ligands of the general formula M(N(2)S(2))R (M = Ga, In; R = Cl, Br, SCN, O(2)CC(6)H(5)-O,O'). The ancillary ligand (Cl, SCN, O(2)CC(6)H(5)-O,O')
Autor:
b Brian S. Haggerty, b and Arnold L. Rheingold, b Glenn P. A. Yap, a Charles H. Winter, a Kumudini C. Jayaratne
Publikováno v:
Inorganic chemistry. 35(17)
Reactions of niobium and tantalum pentachlorides with tert-butylamine (/=6 equiv) in benzene afford the dimeric imido complexes [NbCl(2)(N(t)Bu)(NH(t)Bu)(NH(2)(t)Bu)](2) (90%) and [TaCl(2)(N(t)Bu)(NH(t)Bu)(NH(2)(t)Bu)](2) (79%). The niobium complex e
Publikováno v:
Inorganic Chemistry. 35:5968-5969
The first hydrogen-substituted imido complex of the group 4 metals has been synthesized. Its crystal structure shows the titanium atom in square pyramidal geometry with a very short titanium−nitrog...