Zobrazeno 1 - 10
of 131
pro vyhledávání: '"and Thomas E. Bitterwolf"'
Autor:
Wyatt A. Thornley, Christopher J. Stromberg, Nathan J. DeYonker, Edwin J. Heilweil, Thomas E. Bitterwolf, Maximilian Riedel-Topper, Sarah A. Wirick
Publikováno v:
J Phys Chem B
Two asymmetrically structured model compounds for the hydrogen-generating [Fe-Fe]-hydrogenase active site were investigated to determine the ultrafast photodynamics, structural intermediates, and photoproducts compared to more common symmetric di-iro
Publikováno v:
European Journal of Inorganic Chemistry. 2016:464-468
Photolysis of RuCl3(1-NO)(PPh3)2 in poly(vinyl chloride) (PVC) matrices at 85 K results in reversible linkage isomerism of the nitrosyl ligand to form the isonitrosyl complex RuCl3(1-ON)(PPh3)2. Metal-to-ligand charge-transfer (MLCT) excitation of th
Publikováno v:
Inorganic Chemistry. 54:3370-3375
Photolysis of the permanganate anion, MnO4(-), in tetralkylammonium tetrafluoroborate matrices at 85 K results in formation of a single product, the metastable manganese(V) peroxo complex MnO2(η(2)-O2)(-). Although previously unobserved, this peroxo
Publikováno v:
European Journal of Inorganic Chemistry. 2015:1946-1949
Frozen-matrix photolysis studies of M(CO)2(N2Ph)(PPh3)2 cations (M = Fe and Ru) have revealed end-on/side-on photochemical linkage isomerism of the phenylazo ligand. The previously reported solvent-dependent vibrational bands of the Ru(CO)2(N2Ph)(PPh
Publikováno v:
Angewandte Chemie International Edition. 54:2068-2072
UV photolysis of the nitridoosmate(VIII) anion, OsO3 N(-) , in low-temperature frozen matrices results in nitrogen-oxygen bond formation to give the Os(II) nitrosyl complex OsO2 (NO)(-) . Photolysis of the Os(II) nitrosyl product with visible wavelen
Publikováno v:
ACS Applied Materials & Interfaces. 3:1731-1739
Zinc is one of the most important transition metal of physiological importance, existing primarily as a divalent cation. A number of sensors have been developed for Zn(II) detection. Here, we present a novel fluorescent nanosensor for Zn(II) detectio
Publikováno v:
Applied Surface Science. 257:5766-5771
A thorough analysis of the surface chemistry of silica nanowires has been performed by X-ray photoelectron spectroscopy to investigate unexpected surface changes. Examination of the Si 2p, O 1s, and C 1s core level states before and after exposure of
Autor:
A. Larry Branen, D. Eric Aston, Shiva K. Rastogi, Parul Pal, Thomas E. Bitterwolf, Charlene M. Gibson
Publikováno v:
ACS Applied Materials & Interfaces. 3:279-286
A novel fluorescent zinc sensor was designed and synthesized on ordered mesoporous silica material, MCM-41, with N-(quinolin-8-yl)-2-[3-(triethoxysilyl)propylamino]acetamide (QTEPA; 3) using a simple one-step molecular self-assembly of the silane. Th
Publikováno v:
Inorganica Chimica Acta. 361:3271-3282
Photolysis of cis -Fe(CO) 4 X 2 , where X = Br and I, results in low energy, facile rearrangement to the trans isomer with no evidence of CO-loss. In contrast, the isoelectronic cis -Mn(CO) 4 Br 2 anion exhibits CO-loss upon photolysis with only weak
Autor:
Thomas E. Bitterwolf, Yongsheng Chen, John L. Fulton, Wendy J. Shaw, Anna Gutowska, John C. Linehan
Publikováno v:
Journal of Organometallic Chemistry. 693:2111-2118
A recoverable, water soluble, hydrogenation catalyst was synthesized by reacting poly- N -isopropylacrylamide containing a terminal amino group (H 2 N–CH 2 CH 2 –S–pNIPAAm) with [Rh(CO) 2 Cl] 2 in organic solvents to form the square planar rhod