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Publikováno v:
The Journal of Physical Chemistry A. 101:6568-6576
The tightening of the transition state as energy increases above the dissociation threshold is studied for the dissociation of singlet ketene. Rate constants and quantum yields have been determined...
Publikováno v:
Berichte der Bunsengesellschaft für physikalische Chemie. 101:465-468
The effect of K-conservation on the photodissociation of ketene has been investigated. Rate constants and photofragment excitation (PHOFEX) spectra have been calculated using phase space theory (PST) in a helicity basis. While the effect of K-conserv