Zobrazeno 1 - 10
of 44
pro vyhledávání: '"and Matthew K. Kiesewetter"'
Publikováno v:
Beilstein Journal of Nanotechnology, Vol 14, Iss 1, Pp 865-871 (2023)
N-Heterocyclic carbenes (NHCs) are an emerging alternative to thiols for the formation of stable self-assembled monolayers (SAMs) on gold. We examined several different species that have been used to produce NHC-based monolayers on gold, namely 1,3-d
Externí odkaz:
https://doaj.org/article/1f72e0fb2e474a18bffa420be67c15ba
Autor:
Subhashini Elangovan, Surendra Raj Puri, Hiranya Madawala, Justin Pantano, Brett Pellock, Matthew K. Kiesewetter, Jiyeon Kim
Publikováno v:
Analytical Chemistry. 95:4271-4281
Autor:
U. L. D. Inush Kalana, Elizabeth T. Kiesewetter, Partha P. Datta, Matthew K. Kiesewetter, Rukshika S. Hewawasam
Publikováno v:
Polymer Chemistry. 12:1458-1464
The H-bond mediated organocatalytic ring-opening polymerizations (ROPs) of four new thionolactone monomers are discussed. The kinetic and thermodynamic behavior of the ROPs is considered in the context of the parent lactone monomers. Organocatalysts
Autor:
Matthew K. Kiesewetter, Nayanthara U. Dharmaratne, Oleg I. Kazakov, Timothy J. Bannin, Jinal U. Pothupitiya
Publikováno v:
ACS macro letters. 6(4)
The antibacterial compound, triclocarban (TCC), is shown to be a highly effective H-bond donating catalyst for ring-opening polymerization (ROP) when applied with an H-bond accepting base cocatalyst. These ROPs exhibit the characteristics of “livin
Autor:
Julia J Vieira, Casey L Johnson, Elizabeth M Varkonyi, Howard S Ginsberg, Kassie L Picard, Matthew K Kiesewetter, Steven R Alm
Publikováno v:
Journal of economic entomology. 115(5)
Resistance to traditional synthetic compounds by Varroa destructor Anderson and Trueman and shortcomings of the organic acid class of acaracides commonly used in varroa management requires continual development of new controls. V. destructor, however
Autor:
Elizabeth T. Kiesewetter, Rukshika S. Hewawasam, U. L. D. Inush Kalana, Timothy J. Bannin, Nayanthara U. Dharmaratne, Thomas J. Wright, Matthew K. Kiesewetter
Publikováno v:
Macromolecules. 52:9232-9237
A series of conformationally flexible bis(thio)urea H-bond donors plus base cocatalyst were applied to the ring-opening polymerization (ROP) of lactones. The rate of the ROP displays a strong depen...
Autor:
Matthew K. Kiesewetter, Kurt V. Fastnacht, Danielle N. Coderre, Thomas J. Wright, Nayanthara U. Dharmaratne
Publikováno v:
Macromolecules. 51:10121-10126
The ring-opening polymerization (ROP) kinetics of e-caprolactone and lactide with various H-bonding organocatalysts, (thio)ureas paired with an amine cocatalyst, were evaluated at temperatures up to 110 °C. In nonpolar solvent, most cocatalyst syste
Publikováno v:
Journal of Chemical Education. 96:143-147
In this experiment, students are asked to conduct a catalytic cross-metathesis experiment and compare this reaction to the Wittig reaction within the confines of green chemistry. Students synthesize stilbene from styrene using Grubbs second-generatio
Publikováno v:
Macromolecules. 51:8461-8468
A combined experimental and computational investigation revealed a hydrophobicity trend for oxygen-containing functional groups commonly encountered in monomers and polymers. Based on solvatochroma...
Publikováno v:
Macromolecules. 51:3203-3211
Hammett-style free energy studies of (thio)urea/MTBD mediated ring-opening polymerization (ROP) of δ-valerolactone reveal the complicated interplay of reagents that give rise to catalysis through one of two mechanisms. The operative mechanism depend