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The reaction of Co 3 (CO) 9 CSiCl 3 with polyethylene glycol 400 resulted in the formation of Co 3 (CO) 9 CSi(OR) 3 , R = CH 2 CH 2 (OCH 2 CH 2 ) 9 OH. The latter was used as a catalyst for hydroformylation of hexene in a two-phase system of polyethy
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6704b942cc7af31785b45b93017e60ee
https://doi.org/10.1016/b978-0-12-803530-6.00029-9
https://doi.org/10.1016/b978-0-12-803530-6.00029-9
Publikováno v:
European Journal of Inorganic Chemistry. 2006:628-637
Molybdenum and tungsten complexes with tridentate bisanionic ligands (–OC2H4XC2H4O–, X = S, Se) were synthesized and analyzed electrochemically. Crystal structures of [{MoO2[O(CH2)2S(CH2)2O]}2] and [{WO2[O(CH2)2S(CH2)2O]}3] were obtained. For the
Publikováno v:
European Journal of Inorganic Chemistry. 2005:4840-4844
Chloro(η 5 -pentamethylcyclopentadienyl)(η 2 -pyridine-2-carboxylato)iridium(III) [Ir(η 5 -C 5 Me 5 )(η 2 -C5H4N-2-CO 2 )Cl] (2) and chloro(η 5 -pentamethylcyclopentadienyl)(η 2 -2-(diphenylphosphanyl)thiophenolato]iridium(III) [Ir(η 5 -C 5 Me
Autor:
Herbert W. Roesky, Jörg Magull, Hongping Zhu, Mathias Noltemeyer, Zhi Yang, and Hans-Georg Schmidt
Publikováno v:
Organometallics. 24:6420-6425
Reactions between the aluminum(I) monomer LAl (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) and organic azides (RN3, R = C10H15 (adamantyl), Ph3Si; tBuSi(N3)3) are reported. LAl reacted with the bulky a...
A Stable Aluminacyclopropene LAl(η2-C2H2) and Its End-On Azide Insertion to an Aluminaazacyclobutene
Autor:
Herbert W. Roesky, Vojtech Jancik, Cheng He, Mathias Noltemeyer, Hongping Zhu, Philip P. Power, Hans-Georg Schmidt, Hongjun Fan, William A. Merrill, Jianfang Chai
Publikováno v:
Angewandte Chemie International Edition. 44:5090-5093
Autor:
Hans-Georg Schmidt, Sanjay Singh, S. Shravan Kumar, Mathias Noltemeyer, Herbert W. Roesky, Vojtech Jancik
Publikováno v:
European Journal of Inorganic Chemistry. 2005:3057-3062
The reaction of Au(CO)Cl with 1,3-di-tert-butylimidazol-2-ylidene and 1,3-dimesitylimidazol-2-ylidene in toluene at room temperature results in CO evolution and readily affords in high yield the adducts 1a and 1b, respectively. The reaction of 1a and
Autor:
Umesh N. Nehete, Hongping Zhu, Herbert W. Roesky, Hongjun Fan, Mathias Noltemeyer, Hans-Georg Schmidt, Jianfang Chai
Publikováno v:
European Journal of Inorganic Chemistry. 2005:2147-2150
Reaction of LAl (1) or [LAl{η2-C2(SiMe3)2}] (2) {L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3} with azobenzene affords a five-membered ring compound [LAl{N(H)-o-C6H4N(Ph)}] (3). In the formation of 3 a three-membered intermediate [LAl(η2-N2Ph2)] (A) is s
Publikováno v:
Main Group Chemistry. 4:11-21
1,3-Dialkyl-4,5-dimethylimidazole-2-thiones 1a, 1b and acyclic N,N,N’,N’-tetramethylthiourea 3 react with sulfuryl dichloride to yield a new type of sulfur ylides, 1,3-dialkyl-4,5-dimethylimidazol-2-ylidenesulfonium dichloromethylides 2a, 2b and
Autor:
Mathias Noltemeyer, Guangcai Bai, Jianfang Chai, and Hans-Georg Schmidt, Vojtech Jancik, Cheng He, Hongping Zhu, Herbert W. Roesky
Publikováno v:
Organometallics. 24:380-384
The aluminum chloride iodide LAlClI (2, L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) has been synthesized to study the stepwise hydrolysis of this compound in the presence of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene as hydrogen halide acceptor. The
Autor:
Jianfang Chai, Qingjun Ma, Hans-Georg Schmidt, Herbert W. Roesky, Mathias Noltemeyer, Hongping Zhu
Publikováno v:
European Journal of Inorganic Chemistry. 2004:4807-4811
The reaction of DippNH(CH2)3NHDipp (1) (Dipp = 2,6-iPr2C6H3) with 2 equiv. of MeLi in diethyl ether resulted in the formation of the monomeric dilithium salt [(Dipp)N(CH2)3N(Dipp)][Li(OEt2)]2 (2) in high yield. Further reactions of 2 with MnCl2, FeCl