Zobrazeno 1 - 5
of 5
pro vyhledávání: '"and Gunther H. Grube"'
Publikováno v:
Journal of the American Chemical Society. 123:517-525
Synthesis of a series of corannulene derivatives with varying bowl depths has allowed for a study correlating the structure (bowl depth) and the energy of bowl inversion. Substituents placed in the peri positions are repulsive and flatten the bowl, t
Publikováno v:
Journal of the American Chemical Society. 121:7804-7813
Synthesis of corannulene and alkyl corannulene derivatives has been accomplished using solution-phase chemistry. The key step in the synthesis is the coupling of benzylic bromides of 1,6,7,10-tetraalkylfluoranthene derivatives by low-valent titanium
Publikováno v:
ChemInform. 30
Autor:
Jay S. Siegel, Ralph J. Steffens, Gunther H. Grube, Carissa S. Jones, Kim K. Baldridge, Elliott Eric L
Publikováno v:
Organic letters. 5(5)
Alkyl, aryl, and alkynyl as well as heteroatom derivatives of sym-pentasubstituted corannulenes have been synthesized from sym-pentachlorocorannulene. These units form potential building blocks for future work on superstructures based on corannulene.
Publikováno v:
Journal of the American Chemical Society. 121:7439-7440