Zobrazeno 1 - 10
of 12
pro vyhledávání: '"and Alexander Driess"'
Publikováno v:
Zeitschrift f�r anorganische und allgemeine Chemie. 630:2022-2030
Das Reaktionsverhalten von P(C6H4CH2NMe2-2)3 (1) gegenuber unterschiedlichen Kupfer(II)- und Kupfer(I)-Salzen CuX2 (2a: X = BF4, 2b: X = PF6, 2c: X = ClO4, 2d: X = NO3, 2e: X = Cl, 2f: X = Br, 13: X = O2CMe) und CuX (5a: X = ClO4, 5b: X = NO3, 5c: X
Autor:
L. Zsolnai, Christian Weber, Heinrich Lang, Gottfried Huttner, Hans Pritzkow, Hermann A. Mayer, Gerd Rheinwald, Alexander Driess, M. Melter, M. Leschke
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 628:349-356
The title compounds 3-5 are accessible by treatment of P(C6H4CH2NMe2)3(1) with CuX (2a: X = Cl, 2b: X = Br, 2c: X = I) in the ratio of 1:1 or 1:2 in very good yields. Reaction of 1 with equimolar amounts of 2a affords the copper(I) chloride [P(C6H4CH
Autor:
Gottfried Huttner, M. Melter, M. Leschke, Heinrich Lang, Alexander Driess, Gerd Rheinwald, Christian Weber
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 627:1199-1203
Die Umsetzung des tetrapodalen Phosphans P(C6H4CH2NMe2-2)3 (1) mit aquivalenten Mengen der Silber(I)-Halogenide AgX (2 a: X = Cl, 2 b: X = Br) in Tetrahydrofuran bei 25 °C fuhrt zu den monomeren Silber(I)-Komplexen [P(C6H4CH2NMe2-2)3]AgX mit planare
Autor:
Katrin Köhler, Berthold Schiemenz, Stephan Back, Heinrich Lang, Gottfried Huttner, W. Frosch, H Müller, Alexander Driess
Publikováno v:
Journal of Organometallic Chemistry. 619:99-109
The preparation of numerous donor-functionalised acetylides with Ti(IV) and/or Group II transition metals is described. The reaction of [Ti]Cl2 (1) {[Ti]=(η5-C5H4SiMe3)2Ti} with two equivalents of LiCCR1 [2a: R1=CMeCH2; 2b: R1=C6H4CN-4; 2c:
Autor:
Susanne Mann, Gottfried Huttner, Laszlo Zsolnai, Alexander Driess, Volker Jacob, Katja Heinze, Berthold Schiemenz, Björn Antelmann
Publikováno v:
Zeitschrift für Naturforschung B. 55:638-650
The triphos ligand CH3C(CH2PPh2)3 reacts with Co(BF4)2 (aq) or Fe(BF4)2 (aq) in the presence of nitriles RCN to produce the pentacoordinate [triphosCo(NCR)2](BF4)2 (1) or the hexacoordinate [triphosFe(NCR)3](BF4)2 (2). With α,ω-dinitriles NC-X-CN d
Autor:
Gottfried Huttner, Heinrich Lang, Joachim Strähle, and Katrin Köhler, Gerd Rheinwald, and Alexander Driess, Laszlo Zsolnai, Michael Büchner
Publikováno v:
Organometallics. 18:598-605
The synthesis of heterobimetallic {[Ti](C⋮CR1)2}MX {[Ti] = (η5-C5H4SiMe3)2Ti; M = Cu, R1 = SiMe3: 4a, X = SCF3; 4b, X = SEt; M = Ag, R1 = tBu: 5a, X = OC(O)Me; 5e, X = NO3; M = Ag, R1 = SiMe3: 5...
Autor:
Gottfried Huttner, Michael Büchner, Alexander Driess, Berthold Schiemenz, Katja Heinze, Peter Kircher, Laszlo Zsolnai
Publikováno v:
ResearcherID
The sodium salts Na2[{(CO)5M}2EX2] (M = Cr, Mo, W; E = Ge, Sn, Pb; X = Cl, I, OOCCH3) react with 2,2′-bipyridine (bipy) to form neutral compounds [{(CO)5M}2E(bipy)] (E = Sn: 1a–1c; E = Ge: 3a; E = Pb: 4). 1,10-Phenanthroline (phen) analogues of c
Publikováno v:
Inorganica Chimica Acta. 269:143-156
Various efficient strategies for the preparation of tripod ligands with mixed P/S donor sets such as H 3 CC(CH 2 PPh 2 )(CH 2 SR) (CH 2 SR′) ( 6 ) or three different S donors H 3 CC(CH 2 SR)(CH 2 SR′)(CH 2 SR″) ( 5 ) are described. Compounds 5
Autor:
Sandro Johannes Silverio, Gottfried Huttner, Katrin Köhler, Alexander Driess, Rolf Gleiter, Isabella Hyla-Kryspin, Laszlo Zsolnai, Heinrich Lang
Publikováno v:
Organometallics. 16:4970-4979
The reaction of the bis(alkynyl) titanocenes [Ti](C⋮CR1)(C⋮CR2) ([Ti] = (η5-C5H4SiMe3)2Ti; 1a R1 = R2 = SiMe3; 1b R1 = R2 = tBu; 1c R1 = SiMe3, R2 = tBu) with (C5H5N)AuCl3 (2), LAuCl (5a, L = PPh3; 5b, L = SMe2) as well as (Me2S)AuR3 (6b, R3 = C
Publikováno v:
Journal of Organometallic Chemistry. 541:367-375
Reaction of [MoCl2(PMe3)4] with two equivalents of allylmagnesiumbromide yields the highly reactive bisallylmolybdenum compound [Mo(η1:η2-C3H5)2(PMe3)3], (1). In addition to its X-ray structure analysis its structure in solution is determined NMR s