Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Zh. A. Chobanyan"'
Autor:
N. G. Hobosyan, A. L. Petrosyan, Zh. A. Chobanyan, S. A. Hovakimyan, R. S. Nersisyan, K. V. Balyan
Publikováno v:
Russian Journal of General Chemistry. 87:29-32
General regilarities of the reaction of C-nucleophiles with 1-(prop-2-ynyl)piperidine in the presence of mercuty(II) acetate to form mono-and dicarbonyl derivatives of piperidine and bis[3-(piperidin-1-yl)prop-1-ynyl]mercury. Conditions of these reac
Publikováno v:
Russian Journal of General Chemistry. 86:1011-1016
Regiochemistry of the reaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate has been studied. The possibility of alkylation at the substituted carbon atom of the triple bond of the nitrogen-containin
Publikováno v:
Russian Journal of General Chemistry. 86:267-272
Hydrogenation of terminal β-acetylene alcohols with lithium aluminum hydride in THF has afforded homoallylic alcohols. Decomposition of the intermediate organoaluminum complex with deuterated water, iodine, or pyridinium dibromide has evidenced abou
Publikováno v:
Russian Journal of General Chemistry. 84:2098-2101
Mercuration-demercuration of 2-propyl-2-ynyloxymethyltetrahydrofuran with various nucleophiles has been investigated. Formation of products of hydration, alkylation at the substituted carbon atom of the triple bond, subsequent prototropic isomerizati
Publikováno v:
Russian Journal of General Chemistry. 84:457-464
Hydroalumination-iodination of alkyne-1,4-diols of different structure showed that with increasing number of substituents at the C-OH group the amount of β-iodo-substituted products with respect to this group increased. In the case of symmetric seco
Autor:
K. V. Balyan, A. L. Petrosyan, H. S. Nersisyan, N. G. Hobosyan, A. B. Sargsyan, Zh. A. Chobanyan
Publikováno v:
Russian Journal of Organic Chemistry. 54:1268-1269
Mercuration of a terminal triple bond in pirazoles and triazoles derivatives in the presence of acetylacetone followed by demercuration of intermediates by NaBH4 afforded heterocyclic oxoenol derivatives.
Publikováno v:
Russian Journal of Organic Chemistry. 46:406-409
Methods have been developed for the synthesis of (2E)-1,1-dimethoxyalk-2-en-4-ols and (2E)-4-hydroxyalk-2-enals by reaction of (2E)-4,4-dimethoxybut-2-enals and Grignard compounds. Thermal isomerization of (2E)-4-hydroxyalk-2-enals gave the correspon
Publikováno v:
Russian Journal of Applied Chemistry. 81:455-458
A new procedure for preparing natural alkatrienes, fucoserratene and 1,3,5-undecatrienes, was developed. The key step of both syntheses is stereoselective formation of double bonds by the Wittig reaction starting from (E)-4,4-dimethoxy-2-butenal.
Publikováno v:
Russian Journal of General Chemistry. 83:143-145
The regioand stereochemistry of the hydroalumination was established by the decomposition of the intermediate organometallic complex with deuterium oxide and iodine. The hydride ion was shown to attack the internal carbon atom of acetylene group. The
Publikováno v:
Chemistry of Heterocyclic Compounds. 34:781-784
The regiochemistry of the reaction of propargyl acetate with CH acids in the presence of mercury(II) acetate in dimethylsulfoxide has been investigated. Derivatives of furan or unsaturated diketones were isolated depending on the nature of the 1,3-di