Zobrazeno 1 - 10
of 239
pro vyhledávání: '"Zeev Luz"'
Publikováno v:
Magnetic Resonance in Chemistry. 52:581-594
Enantiodiscrimination in the NMR spectra of flexible prochiral solutes dissolved in chiral liquid crystals (CLCs) is reviewed and compared with the analog phenomenon in such rigid solutes. In rigid prochiral solutes, the discrimination is brought abo
Autor:
Asher Baram, Zeev Luz
Publikováno v:
Israel Journal of Chemistry. 54:196-206
The moments of truncated dynamic magnetic resonance spectra, Mn(L), are expanded in terms of power series of the integration range −L to +L. The expansion consists of three contributions: 1) an L-independent term that, for the first three moments (
Autor:
Noga Friedman, Xiaolin Cao, Zeev Luz, Hailin Zheng, Herbert Zimmermann, Ellen J. Wachtel, Raphy Poupko, Teresa B. Freedman, Laurence A. Nafie
Publikováno v:
The Journal of Physical Chemistry A
The paper concerns the structural and optical isomers of nonamethoxy-tribenzocyclononene (compound 1). In the first part of the paper it is shown that 1 exists in two structural isomers: a rigid crown (c-1) with C3 symmetry and a flexible saddle (s-1
Publikováno v:
Chemical Society Reviews
Chemical Society Reviews, Royal Society of Chemistry, 2015, 44 (8), pp.2330-2375
Chemical Society Reviews, Royal Society of Chemistry, 2015, 44 (8), pp.2330-2375
The splitting of signals in the NMR spectra originating from enantiotopic sites in prochiral molecules when dissolved in chiral solvents is referred to as spectral enantiotopic discrimination. This phenomenon is particularly noticeable in chiral liqu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a24c9980722137b6e2a94ded4f2161be
https://hal.archives-ouvertes.fr/hal-02314352
https://hal.archives-ouvertes.fr/hal-02314352
Publikováno v:
The Journal of Physical Chemistry B
Cyclotriveratrylene (CTV), or hexamethoxy tribenzocyclononatriene (hexamethoxy-TBCN) and other peripherally hexa-(or tri-)substituted TBCN were so far only known to exist in their crown form. Attempts to detect the corresponding saddle isomers failed
Publikováno v:
The Journal of Chemical Physics
We report a 13C NMR investigation of 1,2,3,5,6,7-hexaoctyloxy-rufigallol in the solid and columnar phases using various 2H- and 13C-labeled isotopomers. The measurements were performed under both static and magic-angle spinning conditions. The confor
Publikováno v:
Journal of Physical Chemistry B
Separated local field NMR spectroscopy was used to obtain 1H−13C dipolar interactions in the solid and columnar phases of the discotic compound 1,2,3,5,6,7-hexaoctyloxy-rufigallol (RufH8O). The couplings were measured and assigned by a variety of a
Publikováno v:
Molecular Crystals and Liquid Crystals
A new homologous series of compounds, nonaalkanoyloxy tribenzocyclononene (TBCN-n, where n is the number of carbons per side chain) with n = 2 to 14 was synthesized. The compounds exist in two isomeric forms, crown and saddle. For sufficiently long s
Publikováno v:
Journal of the American Chemical Society
Nona-alkanoyloxy tribenzocyclononene (CTV-n, where n is the number of carbons in the side chains) were prepared for n = 2 to 14. The homologues of this series appear in two stable isomeric forms, rigid crown and flexible saddle. We report on their is
Publikováno v:
Progress in Nuclear Magnetic Resonance Spectroscopy. 41:83-113